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Radical–Chain Reactions of Acetals in Solution

Dilyus Lutfullich Rakhmankulov 1
Dilyus Lutfullich Rakhmankulov
, 
Semen Solomonovich Zlotskii 1
Semen Solomonovich Zlotskii
, 
Vladimir Viktorovich Zorin 1
Vladimir Viktorovich Zorin
, 
Ural Bulatovich Imashev 1
Ural Bulatovich Imashev
, 
Robert Avetisovich Karakhanov 1
Robert Avetisovich Karakhanov
1 Ufa Institute of Oil
10.1070/RC1981v050n08ABEH002672
Published 30 November 1980
Communication , Volume 50, Issue 8, 762-774
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Rakhmankulov D. L. et al. Radical–Chain Reactions of Acetals in Solution // Russian Chemical Reviews. 1981. Vol. 50. No. 8. pp. 762-774.
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Rakhmankulov D. L., Zlotskii S. S., Zorin V. V., Imashev U. B., Karakhanov R. A. Radical–Chain Reactions of Acetals in Solution // Russian Chemical Reviews. 1981. Vol. 50. No. 8. pp. 762-774.
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TY - JOUR
DO - 10.1070/RC1981v050n08ABEH002672
UR - https://rcr.colab.ws/publications/10.1070/RC1981v050n08ABEH002672
TI - Radical–Chain Reactions of Acetals in Solution
T2 - Russian Chemical Reviews
AU - Rakhmankulov, Dilyus Lutfullich
AU - Zlotskii, Semen Solomonovich
AU - Zorin, Vladimir Viktorovich
AU - Imashev, Ural Bulatovich
AU - Karakhanov, Robert Avetisovich
PY - 1981
DA - 1980/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 762-774
IS - 8
VL - 50
ER -
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@article{1981_Rakhmankulov,
author = {Dilyus Lutfullich Rakhmankulov and Semen Solomonovich Zlotskii and Vladimir Viktorovich Zorin and Ural Bulatovich Imashev and Robert Avetisovich Karakhanov},
title = {Radical–Chain Reactions of Acetals in Solution},
journal = {Russian Chemical Reviews},
year = {1981},
volume = {50},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1981v050n08ABEH002672},
number = {8},
pages = {762--774},
doi = {10.1070/RC1981v050n08ABEH002672}
}
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Rakhmankulov, Dilyus Lutfullich, et al. “Radical–Chain Reactions of Acetals in Solution.” Russian Chemical Reviews, vol. 50, no. 8, Nov. 1981, pp. 762-774. https://rcr.colab.ws/publications/10.1070/RC1981v050n08ABEH002672.
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Abstract

Experimental results on the liquid-phase radical–chain reactions of acetals are summarised. Factors influencing the rate of formation, structure, and properties of free radicals generated from cyclic and linear acetals are discussed. Attention is paid mainly to the kinetics and the mechanism of the reactions of mono- and di-alkoxyalkyl radicals in solution. The relation between the structure of acetals and their reactivity towards various radicals is examined. Data are given illustrating the possibility of using homolytic liquid-phase reactions of acetals in organic synthesis. A list of 77 references is included.

References

1.
1
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1948
2.
Electron spin resonance studies. Part XXVII. The geometry of oxygen-substituted alkyl radicals
Dobbs A.J., Gilbert B.C., Norman R.O.
Journal of the Chemical Society A Inorganic Physical Theoretical , 1971
3.
FREE-RADICAL ACETOXY GROUP MIGRATION : AN E.P.R. SPECTRAL STUDY
Beckwith A., Tindal P.
Australian Journal of Chemistry , 1971
4.
The mechanism of the rearrangement of β-acyloxyalkyl radicals
Beckwith A.L., Thomas C.B.
Journal of the Chemical Society Perkin Transactions 2 , 1973
6.
6
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1953
7.
7
E. Rabinowitch
"Photosynthesis" , 1956
8.
8
V. N. Kondrat'ev
"Kinetika Reaktsii v Gazovoi Faze" (Kinetics of Reactions in the Gas Phase) , 1959
9.
9
V. H. Lynch
Carnegie Inst. Year Book , 1954
10.
572. Electron spin resonance studies of oxidation. Part I. Alcohols
Dixon W.T., Norman R.O.
Journal of the Chemical Society (Resumed) , 1963
11.
11
T. T. Bannister
Diss. Abstr. , 1959
13.
13
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1954
14.
14
V. B. Evstigneev
Zhur. Fiz. Khim. , 1958
15.
15
A. S. Holt
"Research in Photosynthesis" , 1957
16.
16
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1949
17.
17
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1958
18.
18
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1951
19.
19
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1959
20.
20
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1954
21.
21
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1958
22.
Reaction of t-Butyl Peroxide with Acetals
KUHN L.P., WELLMAN C.
Journal of Organic Chemistry , 1957
23.
Reactions of Mixed Acetals with Di-t-butyl Peroxide1
Huyser E.S., Wang D.T.
Journal of Organic Chemistry , 1964
24.
24
M. S. Ashkinazi
Dokl. Akad. Nauk SSSR , 1951
25.
25
G. W. Robinson
J. Chem. Phys. , 1955
26.
26
B. Ya. Dain
1957
27.
27
A. A. Krasnovskii
Biofizika , 1956
28.
28
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1955
29.
29
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1951
30.
30
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1954
31.
31
A. A. Krasnovskii
Biokhimiya , 1960
32.
32
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1952
33.
33
M. B. Neiman
"Issledovanie Mekhanizma Okisleniya Butana" (Research on the Mechanism of the Oxidation of Butane) , 1939
34.
34
G. W. Robinson
J. Chem. Phys. , 1886
36.
36
J. Billon
Bull. Soc. chim. France , 1960
37.
37
L. M. Kosobutskaya
Dokl. Akad. Nauk SSSR , 1950
38.
38
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1956
39.
39
V. F. Gachkovskii
Biofizika , 1959
40.
40
A. A. Krasnovskii
Biofizika , 1960
42.
42
L. K. Obukhova
Izv. Akad. Nauk SSSR, Otd. Khim. Nauk , 1960
43.
43
N. Bunge
Ber. Deutsch. Chem. Ges. , 1870
44.
44
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1953
45.
45
W. Hendrich
Roczniki Chemii , 1958
46.
46
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1955
47.
47
G. Oster
"Research in Photosynthesis" , 1957
48.
48
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1955
49.
49
A. A. Krasnovskii
Biofizika , 1958
50.
50
G. Glacomello
Gazzetta. , 1935
51.
51
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1954
52.
52
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1957
53.
Stable dialkoxymethyl halogenides
Scheeren J.W.
Tetrahedron Letters , 1968
55.
55
G. A. Bogdanovskii
1958
56.
56
T. Iasui
Bull. Chem. Soc. Japan. , 1935
57.
57
R. Livingston
"Research in Photosynthesis" , 1957
58.
58
N. E. Khomutov
1953
60.
60
A. N. Terenin
Optika i Spektrosk. , 1956
61.
61
A. N. Terenin
1959
62.
62
A. A. Krasnovskii
"Sbornik, Voprosy Khimicheskoi Kinetiki" (Symposium, Problems of Chemical Kinetics) , 1955
63.
63
1930
64.
The light-induced addition of acetals to olefins
Elad D., Rosenthal I.
Chemical Communications (London) , 1966
65.
Photoalkylation of cyclic acetals
Rosenthal I., Elad D.
Journal of Organic Chemistry , 1968
66.
66
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1950
67.
67
N. N. Mel'nikov
Zhur. Obshch. Khim. , 1940
68.
68
N. N. Mel'nikov
Zhur. Obshch. Khim. , 1946
69.
69
B. Commoner
1958
70.
70
N. Bubnov
Biofizika , 1960
71.
71
Yu. A. Shlyapnikov
Vysokomol. Soed. , 1962
72.
72
A. F. Lukovnikov
"Starenie i Stabilizatsiya Polimerov" (Aging arid Stabilisation of Polymers) , 1963
73.
73
T. Skwarski
Chem. Abs. , 1957
74.
STEREOCHEMISTRY OF THE 2,4-DIMETHYL-1,3-DIOXOLAN-2-YL RADICAL
Kobayashi S.O., Simamura O.
Chemistry Letters , 1973
75.
75
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1950
76.
76
A. N. Terenin
"Fotokhimiya Krasitelei" (The Photochemistry of Dyes) , 1947
77.
77
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1948
78.
78
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1949