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Kinetics of the Thermal Decomposition of N-Nitro-compounds

Fedor Ivanovich Dubovitskii 1
Fedor Ivanovich Dubovitskii
, 
Boris L'vovich Korsunskii 1
Boris L'vovich Korsunskii
1 Institute of Chemical Physics of the USSR Academy of Sciences, Moscow
10.1070/RC1981v050n10ABEH002721
Published 30 November 1980
Communication , Volume 50, Issue 10, 958-978
65
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Dubovitskii F. I., Korsunskii B. L. Kinetics of the Thermal Decomposition of N-Nitro-compounds // Russian Chemical Reviews. 1981. Vol. 50. No. 10. pp. 958-978.
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Dubovitskii F. I., Korsunskii B. L. Kinetics of the Thermal Decomposition of N-Nitro-compounds // Russian Chemical Reviews. 1981. Vol. 50. No. 10. pp. 958-978.
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TY - JOUR
DO - 10.1070/RC1981v050n10ABEH002721
UR - https://rcr.colab.ws/publications/10.1070/RC1981v050n10ABEH002721
TI - Kinetics of the Thermal Decomposition of N-Nitro-compounds
T2 - Russian Chemical Reviews
AU - Dubovitskii, Fedor Ivanovich
AU - Korsunskii, Boris L'vovich
PY - 1981
DA - 1980/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 958-978
IS - 10
VL - 50
ER -
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@article{1981_Dubovitskii,
author = {Fedor Ivanovich Dubovitskii and Boris L'vovich Korsunskii},
title = {Kinetics of the Thermal Decomposition of N-Nitro-compounds},
journal = {Russian Chemical Reviews},
year = {1981},
volume = {50},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1981v050n10ABEH002721},
number = {10},
pages = {958--978},
doi = {10.1070/RC1981v050n10ABEH002721}
}
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Dubovitskii, Fedor Ivanovich, and Boris L'vovich Korsunskii. “Kinetics of the Thermal Decomposition of N-Nitro-compounds.” Russian Chemical Reviews, vol. 50, no. 10, Nov. 1981, pp. 958-978. https://rcr.colab.ws/publications/10.1070/RC1981v050n10ABEH002721.
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Abstract

Results primarily on nitramines are summarised. Analysis of modern views indicates that a non-chain radical mechanism with rupture of the N–NO2 bond in the rate-determining stage is the most soundly based. Kinetic parameters of the thermal decomposition of N-nitro-compounds are systematised. The kinetic role of phase constitution is discussed, and prospects for future research are considered. A list of 108 references is included.