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Oxidation of Organometallic Compounds by Transition Metal Salts

Alexander Nikolaevich Kashin 1
Alexander Nikolaevich Kashin
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1 Lomonosov Moscow State University, Faculty of Chemistry
10.1070/RC1982v051n06ABEH002856
Published 30 November 1981
Communication , Volume 51, Issue 6, 503-526
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Kashin A. N., Beletskaya I. P. Oxidation of Organometallic Compounds by Transition Metal Salts // Russian Chemical Reviews. 1982. Vol. 51. No. 6. pp. 503-526.
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Kashin A. N., Beletskaya I. P. Oxidation of Organometallic Compounds by Transition Metal Salts // Russian Chemical Reviews. 1982. Vol. 51. No. 6. pp. 503-526.
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TY - JOUR
DO - 10.1070/RC1982v051n06ABEH002856
UR - https://rcr.colab.ws/publications/10.1070/RC1982v051n06ABEH002856
TI - Oxidation of Organometallic Compounds by Transition Metal Salts
T2 - Russian Chemical Reviews
AU - Kashin, Alexander Nikolaevich
AU - Beletskaya, Irina Petrovna
PY - 1982
DA - 1981/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 503-526
IS - 6
VL - 51
ER -
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@article{1982_Kashin,
author = {Alexander Nikolaevich Kashin and Irina Petrovna Beletskaya},
title = {Oxidation of Organometallic Compounds by Transition Metal Salts},
journal = {Russian Chemical Reviews},
year = {1982},
volume = {51},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1982v051n06ABEH002856},
number = {6},
pages = {503--526},
doi = {10.1070/RC1982v051n06ABEH002856}
}
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Kashin, Alexander Nikolaevich, and Irina Petrovna Beletskaya. “Oxidation of Organometallic Compounds by Transition Metal Salts.” Russian Chemical Reviews, vol. 51, no. 6, Nov. 1982, pp. 503-526. https://rcr.colab.ws/publications/10.1070/RC1982v051n06ABEH002856.
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Abstract

The mechanisms of one- and two-electron oxidation of organometallic compounds by transition metal salts are considered. It is shown that organometallic compounds can be oxidised as a result of dielectric electron transfer but usually unstable transition metal compounds are formed as intermediates in the reactions. The mechanisms of the thermal and catalytic decomposition of certain types of organometallic compounds are discussed in this connection.
The bibliography includes 244 references.