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Reactivity and Conformation of Systems containing a Three-membered Heterocycle Conjugated with an Unsaturated Group

Alexey Vladimirovich Kamernitskii 1
Alexey Vladimirovich Kamernitskii
, 
Alevtina Mikhailovna Turuta 1
Alevtina Mikhailovna Turuta
1 N. D. Zelinskii Institute of Organic Chemistry of the USSR Academy of Sciences, Moscow
10.1070/RC1982v051n09ABEH002923
Published 30 November 1981
Communication , Volume 51, Issue 9, 872-886
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Kamernitskii A. V., Turuta A. M. Reactivity and Conformation of Systems containing a Three-membered Heterocycle Conjugated with an Unsaturated Group // Russian Chemical Reviews. 1982. Vol. 51. No. 9. pp. 872-886.
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Kamernitskii A. V., Turuta A. M. Reactivity and Conformation of Systems containing a Three-membered Heterocycle Conjugated with an Unsaturated Group // Russian Chemical Reviews. 1982. Vol. 51. No. 9. pp. 872-886.
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TY - JOUR
DO - 10.1070/RC1982v051n09ABEH002923
UR - https://rcr.colab.ws/publications/10.1070/RC1982v051n09ABEH002923
TI - Reactivity and Conformation of Systems containing a Three-membered Heterocycle Conjugated with an Unsaturated Group
T2 - Russian Chemical Reviews
AU - Kamernitskii, Alexey Vladimirovich
AU - Turuta, Alevtina Mikhailovna
PY - 1982
DA - 1981/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 872-886
IS - 9
VL - 51
ER -
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@article{1982_Kamernitskii,
author = {Alexey Vladimirovich Kamernitskii and Alevtina Mikhailovna Turuta},
title = {Reactivity and Conformation of Systems containing a Three-membered Heterocycle Conjugated with an Unsaturated Group},
journal = {Russian Chemical Reviews},
year = {1982},
volume = {51},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1982v051n09ABEH002923},
number = {9},
pages = {872--886},
doi = {10.1070/RC1982v051n09ABEH002923}
}
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Kamernitskii, Alexey Vladimirovich, and Alevtina Mikhailovna Turuta. “Reactivity and Conformation of Systems containing a Three-membered Heterocycle Conjugated with an Unsaturated Group.” Russian Chemical Reviews, vol. 51, no. 9, Nov. 1982, pp. 872-886. https://rcr.colab.ws/publications/10.1070/RC1982v051n09ABEH002923.
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Abstract

Steroidal epoxides, aziridines, and episulphides containing a vicinal unsaturated group (ketone or hydrazone) are used as examples to examine, systematise, and generalise reactions involving nucleophilic opening of a three-membered ring. The influence of an adjacent substituent on the structural and stereochemical trends of such reactions is discussed. A list of 107 references is included.