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Investigation of Paramagnetic Metallocenes and Diarene Complexes of Transition Metals by Magnetic Resonance Methods

Stanislav Panteleimonovich Solodovnikov 1
Stanislav Panteleimonovich Solodovnikov
1 A. N. Nesmeyanov Institute of Organoelement Compounds, USSR Academy of Sciences, Moscow
10.1070/RC1982v051n10ABEH002934
Published 30 November 1981
Communication , Volume 51, Issue 10, 961-974
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Solodovnikov S. P. Investigation of Paramagnetic Metallocenes and Diarene Complexes of Transition Metals by Magnetic Resonance Methods // Russian Chemical Reviews. 1982. Vol. 51. No. 10. pp. 961-974.
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Solodovnikov S. P. Investigation of Paramagnetic Metallocenes and Diarene Complexes of Transition Metals by Magnetic Resonance Methods // Russian Chemical Reviews. 1982. Vol. 51. No. 10. pp. 961-974.
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TY - JOUR
DO - 10.1070/RC1982v051n10ABEH002934
UR - https://rcr.colab.ws/publications/10.1070/RC1982v051n10ABEH002934
TI - Investigation of Paramagnetic Metallocenes and Diarene Complexes of Transition Metals by Magnetic Resonance Methods
T2 - Russian Chemical Reviews
AU - Solodovnikov, Stanislav Panteleimonovich
PY - 1982
DA - 1981/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 961-974
IS - 10
VL - 51
ER -
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@article{1982_Solodovnikov,
author = {Stanislav Panteleimonovich Solodovnikov},
title = {Investigation of Paramagnetic Metallocenes and Diarene Complexes of Transition Metals by Magnetic Resonance Methods},
journal = {Russian Chemical Reviews},
year = {1982},
volume = {51},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1982v051n10ABEH002934},
number = {10},
pages = {961--974},
doi = {10.1070/RC1982v051n10ABEH002934}
}
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Solodovnikov, Stanislav Panteleimonovich. “Investigation of Paramagnetic Metallocenes and Diarene Complexes of Transition Metals by Magnetic Resonance Methods.” Russian Chemical Reviews, vol. 51, no. 10, Nov. 1982, pp. 961-974. https://rcr.colab.ws/publications/10.1070/RC1982v051n10ABEH002934.
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Abstract

EPR and NMR data for paramagnetic metallocenes and diarene complexes of transition metals are presented. The analysis of the g-factors and the hyperfine and spin–spin interaction constants for the EPR spectra as well as the paramagnetic shifts in the NMR spectra have been used to determine the electronic configurations of the complexes. The manifestation of the Jahn–Teller effect in the EPR spectra of sandwich compounds is described. The scheme of the d-electronic levels in metallocenes and the mechanism of the spin delocalisation are discussed.
The bibliography includes 67 references.