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Hydrochlorination of Unsaturated Compounds

Gleb Borisovich Sergeev 1
Gleb Borisovich Sergeev
, 
Vladimir Valentinovich Smirnov 1
Vladimir Valentinovich Smirnov
, 
Tat'yana Nikolaevna Rostovshchikova 1
Tat'yana Nikolaevna Rostovshchikova
1 M. V. Lomonosov Moscow State University, Department of Chemistry
10.1070/RC1983v052n03ABEH002813
Published 30 November 1982
Communication , Volume 52, Issue 3, 259-274
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Sergeev G. B., Smirnov V. V., Rostovshchikova T. N. Hydrochlorination of Unsaturated Compounds // Russian Chemical Reviews. 1983. Vol. 52. No. 3. pp. 259-274.
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Sergeev G. B., Smirnov V. V., Rostovshchikova T. N. Hydrochlorination of Unsaturated Compounds // Russian Chemical Reviews. 1983. Vol. 52. No. 3. pp. 259-274.
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TY - JOUR
DO - 10.1070/RC1983v052n03ABEH002813
UR - https://rcr.colab.ws/publications/10.1070/RC1983v052n03ABEH002813
TI - Hydrochlorination of Unsaturated Compounds
T2 - Russian Chemical Reviews
AU - Sergeev, Gleb Borisovich
AU - Smirnov, Vladimir Valentinovich
AU - Rostovshchikova, Tat'yana Nikolaevna
PY - 1983
DA - 1982/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 259-274
IS - 3
VL - 52
ER -
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@article{1983_Sergeev,
author = {Gleb Borisovich Sergeev and Vladimir Valentinovich Smirnov and Tat'yana Nikolaevna Rostovshchikova},
title = {Hydrochlorination of Unsaturated Compounds},
journal = {Russian Chemical Reviews},
year = {1983},
volume = {52},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1983v052n03ABEH002813},
number = {3},
pages = {259--274},
doi = {10.1070/RC1983v052n03ABEH002813}
}
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Sergeev, Gleb Borisovich, et al. “Hydrochlorination of Unsaturated Compounds.” Russian Chemical Reviews, vol. 52, no. 3, Nov. 1983, pp. 259-274. https://rcr.colab.ws/publications/10.1070/RC1983v052n03ABEH002813.
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Abstract

The mechanism of the hydrochlorination of unsaturated compounds in condensed media is considered on the basis of modern data concerning the kinetics and products of the reaction and also the intermolecular interactions in the reaction system. It is shown that, like other addition processes, hydrochlorination can be carried out in non-polar media at low temperatures without the intermediate formation of ionic species, i.e. via a molecular mechanism. The factors which determine the competition between the ionic and molecular process mechanisms are analysed in detail.
The bibliography includes 184 references.