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Advances in the Chemistry of σ-Derivatives of Group IVB–VIB Transition Metals

Grigorii Alekseevich Razuvaev 1
Grigorii Alekseevich Razuvaev
, 
Lyudmila Ivanovna Vyshinskaya 1
Lyudmila Ivanovna Vyshinskaya
1 Chemistry Research Institute, State University of Gor'kii
10.1070/RC1983v052n10ABEH002907
Published 30 November 1982
Communication , Volume 52, Issue 10, 944-959
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Razuvaev G. A., Vyshinskaya L. I. Advances in the Chemistry of σ-Derivatives of Group IVB–VIB Transition Metals // Russian Chemical Reviews. 1983. Vol. 52. No. 10. pp. 944-959.
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Razuvaev G. A., Vyshinskaya L. I. Advances in the Chemistry of σ-Derivatives of Group IVB–VIB Transition Metals // Russian Chemical Reviews. 1983. Vol. 52. No. 10. pp. 944-959.
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TY - JOUR
DO - 10.1070/RC1983v052n10ABEH002907
UR - https://rcr.colab.ws/publications/10.1070/RC1983v052n10ABEH002907
TI - Advances in the Chemistry of σ-Derivatives of Group IVB–VIB Transition Metals
T2 - Russian Chemical Reviews
AU - Razuvaev, Grigorii Alekseevich
AU - Vyshinskaya, Lyudmila Ivanovna
PY - 1983
DA - 1982/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 944-959
IS - 10
VL - 52
ER -
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@article{1983_Razuvaev,
author = {Grigorii Alekseevich Razuvaev and Lyudmila Ivanovna Vyshinskaya},
title = {Advances in the Chemistry of σ-Derivatives of Group IVB–VIB Transition Metals},
journal = {Russian Chemical Reviews},
year = {1983},
volume = {52},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1983v052n10ABEH002907},
number = {10},
pages = {944--959},
doi = {10.1070/RC1983v052n10ABEH002907}
}
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Razuvaev, Grigorii Alekseevich, and Lyudmila Ivanovna Vyshinskaya. “Advances in the Chemistry of σ-Derivatives of Group IVB–VIB Transition Metals.” Russian Chemical Reviews, vol. 52, no. 10, Nov. 1983, pp. 944-959. https://rcr.colab.ws/publications/10.1070/RC1983v052n10ABEH002907.
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Abstract

A systematic account is given of the literature data on the methods of synthesis and reactivities of transition metal σ-derivatives RnM and RnMXm–n(X = halogen, OR', acac, or NR'2; R' = Me, Et, or Ph; n = valence of the metal) for transition metals in the Ti, V, and Cr subgroups. The influence of the nature of the central atom and of the character of the σ-substituents on the mode of thermal decomposition is discussed. The mechanisms of reactions involving insertion in the transition metal–carbon σ-bond are considered.
The bibliography includes 124 references.