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Negative Temperature Coefficient in Chemical Reactions

I'ya Abramovich Leenson 1
I'ya Abramovich Leenson
, 
Gleb Borisovich Sergeev 1
Gleb Borisovich Sergeev
1 M. V. Lomonosov Moscow State University, Department of Chemistry
10.1070/RC1984v053n05ABEH003060
Published 30 November 1983
Communication , Volume 53, Issue 5, 417-434
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Leenson I. A., Sergeev G. B. Negative Temperature Coefficient in Chemical Reactions // Russian Chemical Reviews. 1984. Vol. 53. No. 5. pp. 417-434.
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Leenson I. A., Sergeev G. B. Negative Temperature Coefficient in Chemical Reactions // Russian Chemical Reviews. 1984. Vol. 53. No. 5. pp. 417-434.
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TY - JOUR
DO - 10.1070/RC1984v053n05ABEH003060
UR - https://rcr.colab.ws/publications/10.1070/RC1984v053n05ABEH003060
TI - Negative Temperature Coefficient in Chemical Reactions
T2 - Russian Chemical Reviews
AU - Leenson, I'ya Abramovich
AU - Sergeev, Gleb Borisovich
PY - 1984
DA - 1983/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 417-434
IS - 5
VL - 53
ER -
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@article{1984_Leenson,
author = {I'ya Abramovich Leenson and Gleb Borisovich Sergeev},
title = {Negative Temperature Coefficient in Chemical Reactions},
journal = {Russian Chemical Reviews},
year = {1984},
volume = {53},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1984v053n05ABEH003060},
number = {5},
pages = {417--434},
doi = {10.1070/RC1984v053n05ABEH003060}
}
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Leenson, I'ya Abramovich, and Gleb Borisovich Sergeev. “Negative Temperature Coefficient in Chemical Reactions.” Russian Chemical Reviews, vol. 53, no. 5, Nov. 1984, pp. 417-434. https://rcr.colab.ws/publications/10.1070/RC1984v053n05ABEH003060.
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Abstract

A systematic analysis of reactions whose rate decreases with increase of temperature is presented. The possibility of a negative temperature coefficient in the elementary reactions is examined from the standpoint of the transition state theory and of collision theory. The mechanisms of complex reactions in which the temperature dependence of the rate is anomalous are discussed, and possible reasons for the anomaly are examined.
The bibliography contains 175 references.