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Solvation Effects and the Mechanism of the Heterolysis of t-Butyl Halides

Genrikh Fedorovich Dvorko 1
Genrikh Fedorovich Dvorko
, 
Engel'sina Aleksandrovna Ponomareva 1
Engel'sina Aleksandrovna Ponomareva
, 
N I Kulik 1
N I Kulik
1 Kiev Polytechnic Institute
10.1070/RC1984v053n06ABEH003074
Published 30 November 1983
Communication , Volume 53, Issue 6, 547-560
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Dvorko G. F., Ponomareva E. A., Kulik N. I. Solvation Effects and the Mechanism of the Heterolysis of t-Butyl Halides // Russian Chemical Reviews. 1984. Vol. 53. No. 6. pp. 547-560.
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Dvorko G. F., Ponomareva E. A., Kulik N. I. Solvation Effects and the Mechanism of the Heterolysis of t-Butyl Halides // Russian Chemical Reviews. 1984. Vol. 53. No. 6. pp. 547-560.
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TY - JOUR
DO - 10.1070/RC1984v053n06ABEH003074
UR - https://rcr.colab.ws/publications/10.1070/RC1984v053n06ABEH003074
TI - Solvation Effects and the Mechanism of the Heterolysis of t-Butyl Halides
T2 - Russian Chemical Reviews
AU - Dvorko, Genrikh Fedorovich
AU - Ponomareva, Engel'sina Aleksandrovna
AU - Kulik, N I
PY - 1984
DA - 1983/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 547-560
IS - 6
VL - 53
ER -
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@article{1984_Dvorko,
author = {Genrikh Fedorovich Dvorko and Engel'sina Aleksandrovna Ponomareva and N I Kulik},
title = {Solvation Effects and the Mechanism of the Heterolysis of t-Butyl Halides},
journal = {Russian Chemical Reviews},
year = {1984},
volume = {53},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1984v053n06ABEH003074},
number = {6},
pages = {547--560},
doi = {10.1070/RC1984v053n06ABEH003074}
}
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Dvorko, Genrikh Fedorovich, et al. “Solvation Effects and the Mechanism of the Heterolysis of t-Butyl Halides.” Russian Chemical Reviews, vol. 53, no. 6, Nov. 1984, pp. 547-560. https://rcr.colab.ws/publications/10.1070/RC1984v053n06ABEH003074.
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Abstract

Data on the kinetics and mechanism of the heterolysis of t-BuX (X = Cl, Br, I) in the gas phase and in individual solvents are surveyed. The mechanism of the unimolecular heterolysis of t-BuX and the role of the solvent in this process are discussed.
The bibliography includes 192 references.