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Structural Disorder and Mechanochemical Reactions in Solids

Pavel Yur'evich Butyagin 1
Pavel Yur'evich Butyagin
1 Institute of Chemical Physics of the USSR Academy of Sciences, Moscow
Published 30 November 1983
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Butyagin P. Y. Structural Disorder and Mechanochemical Reactions in Solids // Russian Chemical Reviews. 1984. Vol. 53. No. 11. pp. 1025-1038.
GOST all authors (up to 50)
Butyagin P. Y. Structural Disorder and Mechanochemical Reactions in Solids // Russian Chemical Reviews. 1984. Vol. 53. No. 11. pp. 1025-1038.
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TY - JOUR
DO - 10.1070/RC1984v053n11ABEH003138
UR - https://rcr.colab.ws/publications/10.1070/RC1984v053n11ABEH003138
TI - Structural Disorder and Mechanochemical Reactions in Solids
T2 - Russian Chemical Reviews
AU - Butyagin, Pavel Yur'evich
PY - 1984
DA - 1983/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 1025-1038
IS - 11
VL - 53
ER -
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@article{1984_Butyagin,
author = {Pavel Yur'evich Butyagin},
title = {Structural Disorder and Mechanochemical Reactions in Solids},
journal = {Russian Chemical Reviews},
year = {1984},
volume = {53},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1984v053n11ABEH003138},
number = {11},
pages = {1025--1038},
doi = {10.1070/RC1984v053n11ABEH003138}
}
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Butyagin, Pavel Yur'evich. “Structural Disorder and Mechanochemical Reactions in Solids.” Russian Chemical Reviews, vol. 53, no. 11, Nov. 1984, pp. 1025-1038. https://rcr.colab.ws/publications/10.1070/RC1984v053n11ABEH003138.
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Abstract

The present review is devoted to an analysis of the relationship between the changes in the structure and reactivity of solids, brought about by the development of a deformation. It has been shown that the principal regular features of mechanochemical transformations are determined by the extent of the structural disorder, the processes involved in its relaxation with the liberation of stored energy, and the mobility of the atoms. The part played by each of these factors has been examined for mechanically activated chemisorption, the ionisation of structural defects, the production of various non-equilibrium states on relaxation, the excitation of the mobility of the structure with the intensification of diffusion-controlled reactions, etc.
The bibliography contains 87 references.