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Regular Kinetic Features of the Dissolution of Metal Oxides in Acidic Media

Igor' Georgievich Gorichev 1
Igor' Georgievich Gorichev
, 
Nikolai Andreevich Kipriyanov 2
Nikolai Andreevich Kipriyanov
1 Moscow State (V. I. Lenin) Pedagogical Institute
2 Correspondence Institute of Soviet Trade, Moscow
10.1070/RC1984v053n11ABEH003139
Published 30 November 1983
Communication , Volume 53, Issue 11, 1039-1061
49
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Gorichev I. G., Kipriyanov N. A. Regular Kinetic Features of the Dissolution of Metal Oxides in Acidic Media // Russian Chemical Reviews. 1984. Vol. 53. No. 11. pp. 1039-1061.
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Gorichev I. G., Kipriyanov N. A. Regular Kinetic Features of the Dissolution of Metal Oxides in Acidic Media // Russian Chemical Reviews. 1984. Vol. 53. No. 11. pp. 1039-1061.
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TY - JOUR
DO - 10.1070/RC1984v053n11ABEH003139
UR - https://rcr.colab.ws/publications/10.1070/RC1984v053n11ABEH003139
TI - Regular Kinetic Features of the Dissolution of Metal Oxides in Acidic Media
T2 - Russian Chemical Reviews
AU - Gorichev, Igor' Georgievich
AU - Kipriyanov, Nikolai Andreevich
PY - 1984
DA - 1983/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 1039-1061
IS - 11
VL - 53
ER -
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@article{1984_Gorichev,
author = {Igor' Georgievich Gorichev and Nikolai Andreevich Kipriyanov},
title = {Regular Kinetic Features of the Dissolution of Metal Oxides in Acidic Media},
journal = {Russian Chemical Reviews},
year = {1984},
volume = {53},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1984v053n11ABEH003139},
number = {11},
pages = {1039--1061},
doi = {10.1070/RC1984v053n11ABEH003139}
}
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Gorichev, Igor' Georgievich, and Nikolai Andreevich Kipriyanov. “Regular Kinetic Features of the Dissolution of Metal Oxides in Acidic Media.” Russian Chemical Reviews, vol. 53, no. 11, Nov. 1984, pp. 1039-1061. https://rcr.colab.ws/publications/10.1070/RC1984v053n11ABEH003139.
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Abstract

A comparative analysis of experimental data and theories interpreting the regular kinetic features of the dissolution of metal oxides in acids has been carried out. Theories of the conjugated transfer of the cations and anions of the oxide to the electrolyte solution do not explain the results obtained. The regular kinetic features of the dissolution of oxide phases have been interpreted for the first time on the basis of the present-day theory of semiconductors, electrochemical concepts, and models of heterogeneous kinetics. The proposed electron–proton mechanism explains all the available data on the kinetics of the dissolution of oxides in mineral acids and complexones.
The bibliography contains 214 references.