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Transition Metal Carbonyls Combined with Hydrogen Donors as Initiators of the Radical Reduction of Trichloromethyl Compounds

Rakhil' Khatskelevna Freidlina 1
Rakhil' Khatskelevna Freidlina
, 
Rashid Gasanovich Gasanov 1
Rashid Gasanovich Gasanov
, 
Nadezhda Alekseevna Kuz'mina 1
Nadezhda Alekseevna Kuz'mina
, 
Elena Tsezarevna Chukovskaya 1
Elena Tsezarevna Chukovskaya
1 A. N. Nesmeyanov Institute of Organoelement Compounds, USSR Academy of Sciences, Moscow
10.1070/RC1985v054n07ABEH003101
Published 30 November 1984
Communication , Volume 54, Issue 7, 662-675
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Freidlina R. K. et al. Transition Metal Carbonyls Combined with Hydrogen Donors as Initiators of the Radical Reduction of Trichloromethyl Compounds // Russian Chemical Reviews. 1985. Vol. 54. No. 7. pp. 662-675.
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Freidlina R. K., Gasanov R. G., Kuz'mina N. A., Chukovskaya E. T. Transition Metal Carbonyls Combined with Hydrogen Donors as Initiators of the Radical Reduction of Trichloromethyl Compounds // Russian Chemical Reviews. 1985. Vol. 54. No. 7. pp. 662-675.
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TY - JOUR
DO - 10.1070/RC1985v054n07ABEH003101
UR - https://rcr.colab.ws/publications/10.1070/RC1985v054n07ABEH003101
TI - Transition Metal Carbonyls Combined with Hydrogen Donors as Initiators of the Radical Reduction of Trichloromethyl Compounds
T2 - Russian Chemical Reviews
AU - Freidlina, Rakhil' Khatskelevna
AU - Gasanov, Rashid Gasanovich
AU - Kuz'mina, Nadezhda Alekseevna
AU - Chukovskaya, Elena Tsezarevna
PY - 1985
DA - 1984/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 662-675
IS - 7
VL - 54
ER -
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@article{1985_Freidlina,
author = {Rakhil' Khatskelevna Freidlina and Rashid Gasanovich Gasanov and Nadezhda Alekseevna Kuz'mina and Elena Tsezarevna Chukovskaya},
title = {Transition Metal Carbonyls Combined with Hydrogen Donors as Initiators of the Radical Reduction of Trichloromethyl Compounds},
journal = {Russian Chemical Reviews},
year = {1985},
volume = {54},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1985v054n07ABEH003101},
number = {7},
pages = {662--675},
doi = {10.1070/RC1985v054n07ABEH003101}
}
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Freidlina, Rakhil' Khatskelevna, et al. “Transition Metal Carbonyls Combined with Hydrogen Donors as Initiators of the Radical Reduction of Trichloromethyl Compounds.” Russian Chemical Reviews, vol. 54, no. 7, Nov. 1985, pp. 662-675. https://rcr.colab.ws/publications/10.1070/RC1985v054n07ABEH003101.
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Abstract

The review is devoted to new redox catalysts of the homolytic reduction of trichloromethyl compounds to dichloromethyl compounds – mononuclear and dinuclear metal carbonyls [Fe(CO)5, Ni(CO)4, M(CO)6 (M = Mo, Cr, W), Mn2(CO)10] in combination with hydrogen donors (secondary alcohols, silicon hydrides, mercaptans, tertiary amines, amides, and tetrahydrofuran).
The results obtained hitherto concerning the development of a new radical-chain method for the reduction of a wide variety of trichloromethyl compounds to the dichloromethyl derivatives are surveyed.
The bibliography includes 78 references.