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Thermal Decomposition and Stabilisation of Poly(vinyl Chloride)

Boris Borisovich Troitskii 1
Boris Borisovich Troitskii
, 
Larisa Semenovna Troitskaya 1
Larisa Semenovna Troitskaya
1 Institute of Chemistry, Academy of Sciences of the USSR, Gor'kii
10.1070/RC1985v054n08ABEH003109
Published 30 November 1984
Communication , Volume 54, Issue 8, 755-769
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Troitskii B. B., Troitskaya L. S. Thermal Decomposition and Stabilisation of Poly(vinyl Chloride) // Russian Chemical Reviews. 1985. Vol. 54. No. 8. pp. 755-769.
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Troitskii B. B., Troitskaya L. S. Thermal Decomposition and Stabilisation of Poly(vinyl Chloride) // Russian Chemical Reviews. 1985. Vol. 54. No. 8. pp. 755-769.
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TY - JOUR
DO - 10.1070/RC1985v054n08ABEH003109
UR - https://rcr.colab.ws/publications/10.1070/RC1985v054n08ABEH003109
TI - Thermal Decomposition and Stabilisation of Poly(vinyl Chloride)
T2 - Russian Chemical Reviews
AU - Troitskii, Boris Borisovich
AU - Troitskaya, Larisa Semenovna
PY - 1985
DA - 1984/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 755-769
IS - 8
VL - 54
ER -
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@article{1985_Troitskii,
author = {Boris Borisovich Troitskii and Larisa Semenovna Troitskaya},
title = {Thermal Decomposition and Stabilisation of Poly(vinyl Chloride)},
journal = {Russian Chemical Reviews},
year = {1985},
volume = {54},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1985v054n08ABEH003109},
number = {8},
pages = {755--769},
doi = {10.1070/RC1985v054n08ABEH003109}
}
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Troitskii, Boris Borisovich, and Larisa Semenovna Troitskaya. “Thermal Decomposition and Stabilisation of Poly(vinyl Chloride).” Russian Chemical Reviews, vol. 54, no. 8, Nov. 1985, pp. 755-769. https://rcr.colab.ws/publications/10.1070/RC1985v054n08ABEH003109.
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Abstract

The kinetics and mechanism of the thermal dehydrochlorination of poly(vinyl chloride) and low-molecular-weight chlorohydrocarbons which model various fragments of the polymer molecule, are discussed. Studies designed to determine the qualitative and quantitative compositions of the unstable fragments in poly(vinyl chloride) macromolecules by 13C NMR are examined. Attention is concentrated on the consideration of the mechanism of the action of the most effective thermostabilisers for the polymer – organotin compounds. The principal features of synergism in the stabilisation of poly(vinyl chloride) and the mechanism of the action of synergistic mixtures are analysed.
The bibliography includes 107 references.