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The Structure of the Active Centres and Stereoregulation in the Ionic–Coordination Polymerisation of α-Alkenes and 1,3-Dienes on Ziegler–Natta Catalysts

Karl Samoilovich Minsker 1
Karl Samoilovich Minsker
, 
Mark Mikhailovich Karpasas 1
Mark Mikhailovich Karpasas
, 
Gennadii Efremovich Zaikov 2
Gennadii Efremovich Zaikov
1 Bashkir State University, Ufa
2 Institute of Chemical Physics of the USSR Academy of Sciences, Moscow
10.1070/RC1986v055n01ABEH003169
Published 30 November 1985
Communication , Volume 55, Issue 1, 17-38
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Minsker K. S., Karpasas M. M., Zaikov G. E. The Structure of the Active Centres and Stereoregulation in the Ionic–Coordination Polymerisation of α-Alkenes and 1,3-Dienes on Ziegler–Natta Catalysts // Russian Chemical Reviews. 1986. Vol. 55. No. 1. pp. 17-38.
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Minsker K. S., Karpasas M. M., Zaikov G. E. The Structure of the Active Centres and Stereoregulation in the Ionic–Coordination Polymerisation of α-Alkenes and 1,3-Dienes on Ziegler–Natta Catalysts // Russian Chemical Reviews. 1986. Vol. 55. No. 1. pp. 17-38.
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TY - JOUR
DO - 10.1070/RC1986v055n01ABEH003169
UR - https://rcr.colab.ws/publications/10.1070/RC1986v055n01ABEH003169
TI - The Structure of the Active Centres and Stereoregulation in the Ionic–Coordination Polymerisation of α-Alkenes and 1,3-Dienes on Ziegler–Natta Catalysts
T2 - Russian Chemical Reviews
AU - Minsker, Karl Samoilovich
AU - Karpasas, Mark Mikhailovich
AU - Zaikov, Gennadii Efremovich
PY - 1986
DA - 1985/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 17-38
IS - 1
VL - 55
ER -
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@article{1986_Minsker,
author = {Karl Samoilovich Minsker and Mark Mikhailovich Karpasas and Gennadii Efremovich Zaikov},
title = {The Structure of the Active Centres and Stereoregulation in the Ionic–Coordination Polymerisation of α-Alkenes and 1,3-Dienes on Ziegler–Natta Catalysts},
journal = {Russian Chemical Reviews},
year = {1986},
volume = {55},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1986v055n01ABEH003169},
number = {1},
pages = {17--38},
doi = {10.1070/RC1986v055n01ABEH003169}
}
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Minsker, Karl Samoilovich, et al. “The Structure of the Active Centres and Stereoregulation in the Ionic–Coordination Polymerisation of α-Alkenes and 1,3-Dienes on Ziegler–Natta Catalysts.” Russian Chemical Reviews, vol. 55, no. 1, Nov. 1986, pp. 17-38. https://rcr.colab.ws/publications/10.1070/RC1986v055n01ABEH003169.
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Abstract

The development of theories of the mechanism of the stereospecific polymerisation of α-alkenes and dienes on Ziegler–Natta catalysts has been examined. Theories of the formation and structure of the active centres, the role of the heterogeneous component of the catalyst, the mechanism of chain initiation and growth, and the mechanism of stereoregulation in the polymerisation of alkenes and dienes have been discussed.
The bibliography contains 115 references.