Home / Articles / Ferrocenyl Carbonium Ions and Related Cationic Complexes. Structure and Stabilisation Mechanism

Ferrocenyl Carbonium Ions and Related Cationic Complexes. Structure and Stabilisation Mechanism

Avtandil Aleksandrovich Koridze 1
Avtandil Aleksandrovich Koridze
1 A. N. Nesmeyanov Institute of Organoelement Compounds, USSR Academy of Sciences, Moscow
10.1070/RC1986v055n02ABEH003175
Published 30 November 1985
Communication , Volume 55, Issue 2, 113-126
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Koridze A. A. Ferrocenyl Carbonium Ions and Related Cationic Complexes. Structure and Stabilisation Mechanism // Russian Chemical Reviews. 1986. Vol. 55. No. 2. pp. 113-126.
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Koridze A. A. Ferrocenyl Carbonium Ions and Related Cationic Complexes. Structure and Stabilisation Mechanism // Russian Chemical Reviews. 1986. Vol. 55. No. 2. pp. 113-126.
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TY - JOUR
DO - 10.1070/RC1986v055n02ABEH003175
UR - https://rcr.colab.ws/publications/10.1070/RC1986v055n02ABEH003175
TI - Ferrocenyl Carbonium Ions and Related Cationic Complexes. Structure and Stabilisation Mechanism
T2 - Russian Chemical Reviews
AU - Koridze, Avtandil Aleksandrovich
PY - 1986
DA - 1985/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 113-126
IS - 2
VL - 55
ER -
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@article{1986_Koridze,
author = {Avtandil Aleksandrovich Koridze},
title = {Ferrocenyl Carbonium Ions and Related Cationic Complexes. Structure and Stabilisation Mechanism},
journal = {Russian Chemical Reviews},
year = {1986},
volume = {55},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1986v055n02ABEH003175},
number = {2},
pages = {113--126},
doi = {10.1070/RC1986v055n02ABEH003175}
}
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Koridze, Avtandil Aleksandrovich. “Ferrocenyl Carbonium Ions and Related Cationic Complexes. Structure and Stabilisation Mechanism.” Russian Chemical Reviews, vol. 55, no. 2, Nov. 1986, pp. 113-126. https://rcr.colab.ws/publications/10.1070/RC1986v055n02ABEH003175.
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Abstract

The review presents data on the structure and mechanism of the stabilisation of ferrocenyl carbonium ions and related cationic complexes with different types of hydrocarbon ligands. The results obtained in the study of complex carbonium ions by X-ray diffraction, 57Fe Mössbauer spectroscopy, and 1H, 13C, 19F, 57Fe, and 187Os NMR are compared. It is shown that the ability of the metal atom to interact directly with the carbonium ion centre generated in the β-position relative to it is a general property of transition metal complexes.
The bibliography includes 132 references.