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Nucleophilic Substitution Reactions. Modern Ideas About the Mechanism and Reactivity

Mikhail Viktorovich Basilevsky 1
Mikhail Viktorovich Basilevsky
, 
S G Koldobskii 1
S G Koldobskii
, 
Vyacheslav Aleksandrovich Tikhomirov 1
Vyacheslav Aleksandrovich Tikhomirov
1 Karpov Institute of Physical Chemistry, Moscow
10.1070/RC1986v055n10ABEH003233
Published 30 November 1985
Communication , Volume 55, Issue 10, 948-965
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Basilevsky M. V., Koldobskii S. G., Tikhomirov V. A. Nucleophilic Substitution Reactions. Modern Ideas About the Mechanism and Reactivity // Russian Chemical Reviews. 1986. Vol. 55. No. 10. pp. 948-965.
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Basilevsky M. V., Koldobskii S. G., Tikhomirov V. A. Nucleophilic Substitution Reactions. Modern Ideas About the Mechanism and Reactivity // Russian Chemical Reviews. 1986. Vol. 55. No. 10. pp. 948-965.
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TY - JOUR
DO - 10.1070/RC1986v055n10ABEH003233
UR - https://rcr.colab.ws/publications/10.1070/RC1986v055n10ABEH003233
TI - Nucleophilic Substitution Reactions. Modern Ideas About the Mechanism and Reactivity
T2 - Russian Chemical Reviews
AU - Basilevsky, Mikhail Viktorovich
AU - Koldobskii, S G
AU - Tikhomirov, Vyacheslav Aleksandrovich
PY - 1986
DA - 1985/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 948-965
IS - 10
VL - 55
ER -
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@article{1986_Basilevsky,
author = {Mikhail Viktorovich Basilevsky and S G Koldobskii and Vyacheslav Aleksandrovich Tikhomirov},
title = {Nucleophilic Substitution Reactions. Modern Ideas About the Mechanism and Reactivity},
journal = {Russian Chemical Reviews},
year = {1986},
volume = {55},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1986v055n10ABEH003233},
number = {10},
pages = {948--965},
doi = {10.1070/RC1986v055n10ABEH003233}
}
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Basilevsky, Mikhail Viktorovich, et al. “Nucleophilic Substitution Reactions. Modern Ideas About the Mechanism and Reactivity.” Russian Chemical Reviews, vol. 55, no. 10, Nov. 1986, pp. 948-965. https://rcr.colab.ws/publications/10.1070/RC1986v055n10ABEH003233.
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Abstract

The mechanism of SN2 reactions is discussed on the basis of gas-phase experimental data and quantum-chemical calculations: the energy relations, stereochemistry, and the form of the potential energy surface. The results of modern kinetic measurements and calculations are presented. The experimental data for the reactions in solution are discussed at the level of qualitative quantum-chemical concepts. The causes of the strong influence of the solvent on the kinetics of these reactions are analysed and the empirical correlations between the kinetic and thermodynamic characteristics and the link between the correlations and modern theoretical ideas are examined.
The bibliography includes 134 references.