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Stable Radicals and the Kinetics of the Radical Polymerisation of Vinyl Monomers

Eduard Grigor'evich Rozantsev 1
Eduard Grigor'evich Rozantsev
, 
Mark Davidovich Gol'dfein 2
Mark Davidovich Gol'dfein
, 
Aleksandr Vladimirovich Trubnikov 2
Aleksandr Vladimirovich Trubnikov
1 Moscow Technological Institute of Meat and Dairy Industry
2 Saratov State University named after N. G. Chernyshevsky
10.1070/RC1986v055n11ABEH003242
Published 30 November 1985
Communication , Volume 55, Issue 11, 1070-1080
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Rozantsev E. G., Gol'dfein M. D., Trubnikov A. V. Stable Radicals and the Kinetics of the Radical Polymerisation of Vinyl Monomers // Russian Chemical Reviews. 1986. Vol. 55. No. 11. pp. 1070-1080.
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Rozantsev E. G., Gol'dfein M. D., Trubnikov A. V. Stable Radicals and the Kinetics of the Radical Polymerisation of Vinyl Monomers // Russian Chemical Reviews. 1986. Vol. 55. No. 11. pp. 1070-1080.
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TY - JOUR
DO - 10.1070/RC1986v055n11ABEH003242
UR - https://rcr.colab.ws/publications/10.1070/RC1986v055n11ABEH003242
TI - Stable Radicals and the Kinetics of the Radical Polymerisation of Vinyl Monomers
T2 - Russian Chemical Reviews
AU - Rozantsev, Eduard Grigor'evich
AU - Gol'dfein, Mark Davidovich
AU - Trubnikov, Aleksandr Vladimirovich
PY - 1986
DA - 1985/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 1070-1080
IS - 11
VL - 55
ER -
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@article{1986_Rozantsev,
author = {Eduard Grigor'evich Rozantsev and Mark Davidovich Gol'dfein and Aleksandr Vladimirovich Trubnikov},
title = {Stable Radicals and the Kinetics of the Radical Polymerisation of Vinyl Monomers},
journal = {Russian Chemical Reviews},
year = {1986},
volume = {55},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1986v055n11ABEH003242},
number = {11},
pages = {1070--1080},
doi = {10.1070/RC1986v055n11ABEH003242}
}
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Rozantsev, Eduard Grigor'evich, et al. “Stable Radicals and the Kinetics of the Radical Polymerisation of Vinyl Monomers.” Russian Chemical Reviews, vol. 55, no. 11, Nov. 1986, pp. 1070-1080. https://rcr.colab.ws/publications/10.1070/RC1986v055n11ABEH003242.
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Abstract

The literature data and the results of studies by the authors of the review on the kinetics and mechanism of the radical polymerisation of vinyl monomers in the presence of stable radicals of different classes are treated systematically and discussed. The principal kinetic features associated with the influence of the structure of the monomer and the stable radical, the type of initiation, and the nature of the initiator on the polymerisation inhibited by stable radicals are noted. Equations are presented for the calculation of the kinetic parameters of the principal elementary reactions responsible for the initiating and inhibiting effect of stable radicals.
The bibliography includes 155 references.