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Norbornadienes in the Synthesis of Polycyclic Strained Hydrocarbons with Participation of Metal Complex Catalysts

, 
Ravil Ismagilovich Khusnutdinov 1
Ravil Ismagilovich Khusnutdinov
, 
Genrikh Alexandrovich Tolstikov 1
Genrikh Alexandrovich Tolstikov
1 Institute of Chemistry of the Bashkir Scientific Center, Ural Branch of the USSR, Ufa
10.1070/RC1987v056n01ABEH003255
Published 30 November 1986
Communication , Volume 56, Issue 1, 36-51
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Dzhemilev U. M., Khusnutdinov R. I., Tolstikov G. A. Norbornadienes in the Synthesis of Polycyclic Strained Hydrocarbons with Participation of Metal Complex Catalysts // Russian Chemical Reviews. 1987. Vol. 56. No. 1. pp. 36-51.
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Dzhemilev U. M., Khusnutdinov R. I., Tolstikov G. A. Norbornadienes in the Synthesis of Polycyclic Strained Hydrocarbons with Participation of Metal Complex Catalysts // Russian Chemical Reviews. 1987. Vol. 56. No. 1. pp. 36-51.
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TY - JOUR
DO - 10.1070/RC1987v056n01ABEH003255
UR - https://rcr.colab.ws/publications/10.1070/RC1987v056n01ABEH003255
TI - Norbornadienes in the Synthesis of Polycyclic Strained Hydrocarbons with Participation of Metal Complex Catalysts
T2 - Russian Chemical Reviews
AU - Dzhemilev, Usein Memetovich
AU - Khusnutdinov, Ravil Ismagilovich
AU - Tolstikov, Genrikh Alexandrovich
PY - 1987
DA - 1986/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 36-51
IS - 1
VL - 56
ER -
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@article{1987_Dzhemilev,
author = {Usein Memetovich Dzhemilev and Ravil Ismagilovich Khusnutdinov and Genrikh Alexandrovich Tolstikov},
title = {Norbornadienes in the Synthesis of Polycyclic Strained Hydrocarbons with Participation of Metal Complex Catalysts},
journal = {Russian Chemical Reviews},
year = {1987},
volume = {56},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1987v056n01ABEH003255},
number = {1},
pages = {36--51},
doi = {10.1070/RC1987v056n01ABEH003255}
}
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Dzhemilev, Usein Memetovich, et al. “Norbornadienes in the Synthesis of Polycyclic Strained Hydrocarbons with Participation of Metal Complex Catalysts.” Russian Chemical Reviews, vol. 56, no. 1, Nov. 1987, pp. 36-51. https://rcr.colab.ws/publications/10.1070/RC1987v056n01ABEH003255.
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Abstract

The advances achieved in recent years in the synthesis of polycyclic hydrocarbons, including those containing functional substituents, from norbornadiene and its derivatives using metal complex catalysts are surveyed. The homo- and codimerisation reactions of norbornadienes with olefins, dienes, and acetylenes, involving the [2π + 2π] -, [2π + 2π + 2π] -, and [4π + 4π] -addition under the influence of transition metal complexes are examined. Data on the synthesis of norbornadiene trimers as well as the physicochemical and spectroscopic characteristics of a whole series of unique hydrocarbons are presented. The mechanisms of the reactions indicated are discussed.
The bibliography includes 173 references.