Home / Articles / The Reactions of Azoxybenzenes in Acids. The Mechanism of the Wallach Rearrangement

The Reactions of Azoxybenzenes in Acids. The Mechanism of the Wallach Rearrangement

Georgii Georgievich Furin 1
Georgii Georgievich Furin
1 Novosibirsk Institute of Organic Chemistry of USSR Academy of Sciences, Siberian Branch
10.1070/RC1987v056n06ABEH003288
Published 30 November 1986
Communication , Volume 56, Issue 6, 532-545
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Furin G. G. The Reactions of Azoxybenzenes in Acids. The Mechanism of the Wallach Rearrangement // Russian Chemical Reviews. 1987. Vol. 56. No. 6. pp. 532-545.
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Furin G. G. The Reactions of Azoxybenzenes in Acids. The Mechanism of the Wallach Rearrangement // Russian Chemical Reviews. 1987. Vol. 56. No. 6. pp. 532-545.
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TY - JOUR
DO - 10.1070/RC1987v056n06ABEH003288
UR - https://rcr.colab.ws/publications/10.1070/RC1987v056n06ABEH003288
TI - The Reactions of Azoxybenzenes in Acids. The Mechanism of the Wallach Rearrangement
T2 - Russian Chemical Reviews
AU - Furin, Georgii Georgievich
PY - 1987
DA - 1986/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 532-545
IS - 6
VL - 56
ER -
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@article{1987_Furin,
author = {Georgii Georgievich Furin},
title = {The Reactions of Azoxybenzenes in Acids. The Mechanism of the Wallach Rearrangement},
journal = {Russian Chemical Reviews},
year = {1987},
volume = {56},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1987v056n06ABEH003288},
number = {6},
pages = {532--545},
doi = {10.1070/RC1987v056n06ABEH003288}
}
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Furin, Georgii Georgievich. “The Reactions of Azoxybenzenes in Acids. The Mechanism of the Wallach Rearrangement.” Russian Chemical Reviews, vol. 56, no. 6, Nov. 1987, pp. 532-545. https://rcr.colab.ws/publications/10.1070/RC1987v056n06ABEH003288.
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Abstract

Data concerning the use of various acids to effect the Wallach rearrangement in the series of azoxybenzenes are analysed and the influence of the chemical nature and position of the substituents on the reactions of azoxybenzenes in the presence of acids, including the Wallach rearrangement and side processes, are examined. Data obtained in the study of the mechanism of the Wallach rearrangement by kinetic and tracer atom methods are discussed and the effect of Lewis acids and UV radiation on azoxybenzenes is considered.
The bibliography includes 63 references.