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The Cleavage of the Carbon–Carbon Bond in Carbonyl Compounds and Alcohols under the Influence of Bases

Galina Anisimovna Artamkina 1
Galina Anisimovna Artamkina
, 
1 M. V. Lomonosov Moscow State University, Department of Chemistry
10.1070/RC1987v056n10ABEH003317
Published 30 November 1986
Communication , Volume 56, Issue 10, 983-1001
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Artamkina G. A., Beletskaya I. P. The Cleavage of the Carbon–Carbon Bond in Carbonyl Compounds and Alcohols under the Influence of Bases // Russian Chemical Reviews. 1987. Vol. 56. No. 10. pp. 983-1001.
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Artamkina G. A., Beletskaya I. P. The Cleavage of the Carbon–Carbon Bond in Carbonyl Compounds and Alcohols under the Influence of Bases // Russian Chemical Reviews. 1987. Vol. 56. No. 10. pp. 983-1001.
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TY - JOUR
DO - 10.1070/RC1987v056n10ABEH003317
UR - https://rcr.colab.ws/publications/10.1070/RC1987v056n10ABEH003317
TI - The Cleavage of the Carbon–Carbon Bond in Carbonyl Compounds and Alcohols under the Influence of Bases
T2 - Russian Chemical Reviews
AU - Artamkina, Galina Anisimovna
AU - Beletskaya, Irina Petrovna
PY - 1987
DA - 1986/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 983-1001
IS - 10
VL - 56
ER -
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@article{1987_Artamkina,
author = {Galina Anisimovna Artamkina and Irina Petrovna Beletskaya},
title = {The Cleavage of the Carbon–Carbon Bond in Carbonyl Compounds and Alcohols under the Influence of Bases},
journal = {Russian Chemical Reviews},
year = {1987},
volume = {56},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1987v056n10ABEH003317},
number = {10},
pages = {983--1001},
doi = {10.1070/RC1987v056n10ABEH003317}
}
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Artamkina, Galina Anisimovna, and Irina Petrovna Beletskaya. “The Cleavage of the Carbon–Carbon Bond in Carbonyl Compounds and Alcohols under the Influence of Bases.” Russian Chemical Reviews, vol. 56, no. 10, Nov. 1987, pp. 983-1001. https://rcr.colab.ws/publications/10.1070/RC1987v056n10ABEH003317.
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Abstract

The characteristics of the cleavage of the carbon–carbon bond in carbonyl compounds and alcohols of different types are considered. It is shown that the ease of dissociation of this bond is determined primarily by the stability of the carbanion formed. Among other factors, the nature of the solvent, the base, and the counterion are important. The importance of the latter factor has the greatest influence on the stability of the O–M bond in alcohols and hydroxycarbonyl compounds.
The bibliography includes 281 references.