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Directly Bonded 13C–13C Spin–Spin Coupling Constants in Structural Studies

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Gennadii Aleksandrovich Kalabin 1
Gennadii Aleksandrovich Kalabin
1 Irkutsk State University
10.1070/RC1988v057n01ABEH003330
Published 30 November 1987
Communication , Volume 57, Issue 1, 1-16
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Krivdin L. B., Kalabin G. A. Directly Bonded 13C–13C Spin–Spin Coupling Constants in Structural Studies // Russian Chemical Reviews. 1988. Vol. 57. No. 1. pp. 1-16.
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Krivdin L. B., Kalabin G. A. Directly Bonded 13C–13C Spin–Spin Coupling Constants in Structural Studies // Russian Chemical Reviews. 1988. Vol. 57. No. 1. pp. 1-16.
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TY - JOUR
DO - 10.1070/RC1988v057n01ABEH003330
UR - https://rcr.colab.ws/publications/10.1070/RC1988v057n01ABEH003330
TI - Directly Bonded 13C–13C Spin–Spin Coupling Constants in Structural Studies
T2 - Russian Chemical Reviews
AU - Krivdin, Leonid Borisovich
AU - Kalabin, Gennadii Aleksandrovich
PY - 1988
DA - 1987/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 1-16
IS - 1
VL - 57
ER -
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@article{1988_Krivdin,
author = {Leonid Borisovich Krivdin and Gennadii Aleksandrovich Kalabin},
title = {Directly Bonded 13C–13C Spin–Spin Coupling Constants in Structural Studies},
journal = {Russian Chemical Reviews},
year = {1988},
volume = {57},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1988v057n01ABEH003330},
number = {1},
pages = {1--16},
doi = {10.1070/RC1988v057n01ABEH003330}
}
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Krivdin, Leonid Borisovich, and Gennadii Aleksandrovich Kalabin. “Directly Bonded 13C–13C Spin–Spin Coupling Constants in Structural Studies.” Russian Chemical Reviews, vol. 57, no. 1, Nov. 1988, pp. 1-16. https://rcr.colab.ws/publications/10.1070/RC1988v057n01ABEH003330.
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Abstract

The review presents the present state of research into the directly bonded 13C–13C spin–spin coupling constants (SSCC) — the parameters of NMR spectra which are most difficult to measure and which contain unique structural information. The principal factors determining the magnitude of the direct 13C–13C SSCC, namely the hybridisation of the interacting atoms, the electronic influence of substituents, steric and solvation effects, and the influence of the unshared electron pairs of the heteroatoms, are analysed. The possibilities of using the directly bonded 13C–13C SSCC for the solution of a wide variety of structural problems in chemistry are examined; special attention is devoted to the prospects for the employment of these parameters in stereochemistry and conformational analysis.
The bibliography includes 232 references.