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The Kinetic Stability of Biscyclopentadienyl and Diarene Compounds of Transition Metals in the Thermal Decomposition Reaction

Lyudmila Mikhailovna Dyagileva 1
Lyudmila Mikhailovna Dyagileva
, 
Elena Ivanovna Tsyganova 1
Elena Ivanovna Tsyganova
, 
Yurii Arsent'evich Aleksandrov 1
Yurii Arsent'evich Aleksandrov
1 Chemistry Research Institute of N. I. Lobachevsky, State University of Gorky
10.1070/RC1988v057n04ABEH003352
Published 30 November 1987
Communication , Volume 57, Issue 4, 316-325
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Dyagileva L. M., Tsyganova E. I., Aleksandrov Y. A. The Kinetic Stability of Biscyclopentadienyl and Diarene Compounds of Transition Metals in the Thermal Decomposition Reaction // Russian Chemical Reviews. 1988. Vol. 57. No. 4. pp. 316-325.
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Dyagileva L. M., Tsyganova E. I., Aleksandrov Y. A. The Kinetic Stability of Biscyclopentadienyl and Diarene Compounds of Transition Metals in the Thermal Decomposition Reaction // Russian Chemical Reviews. 1988. Vol. 57. No. 4. pp. 316-325.
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TY - JOUR
DO - 10.1070/RC1988v057n04ABEH003352
UR - https://rcr.colab.ws/publications/10.1070/RC1988v057n04ABEH003352
TI - The Kinetic Stability of Biscyclopentadienyl and Diarene Compounds of Transition Metals in the Thermal Decomposition Reaction
T2 - Russian Chemical Reviews
AU - Dyagileva, Lyudmila Mikhailovna
AU - Tsyganova, Elena Ivanovna
AU - Aleksandrov, Yurii Arsent'evich
PY - 1988
DA - 1987/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 316-325
IS - 4
VL - 57
ER -
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@article{1988_Dyagileva,
author = {Lyudmila Mikhailovna Dyagileva and Elena Ivanovna Tsyganova and Yurii Arsent'evich Aleksandrov},
title = {The Kinetic Stability of Biscyclopentadienyl and Diarene Compounds of Transition Metals in the Thermal Decomposition Reaction},
journal = {Russian Chemical Reviews},
year = {1988},
volume = {57},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1988v057n04ABEH003352},
number = {4},
pages = {316--325},
doi = {10.1070/RC1988v057n04ABEH003352}
}
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Dyagileva, Lyudmila Mikhailovna, et al. “The Kinetic Stability of Biscyclopentadienyl and Diarene Compounds of Transition Metals in the Thermal Decomposition Reaction.” Russian Chemical Reviews, vol. 57, no. 4, Nov. 1988, pp. 316-325. https://rcr.colab.ws/publications/10.1070/RC1988v057n04ABEH003352.
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Abstract

Literature data on the kinetic stability of mononuclear metallocene and diarene derivatives of transition metals are described systematically and discussed. A relation between the reactivity of the π-complexes in the thermal decomposition reaction and their structure (the nature of the central metal atom, the σ-substituent, and the π-ligand) has been discovered, surface effects and the role of the adsorption of organometallic compounds in pyrolysis are examined, and problems of macrokinetics are discussed.
The bibliography includes 106 references.