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NMR Spectroscopy of Polyfluorinated Allyl Cations

Vladimir Ivanovich Bakhmutov 1
Vladimir Ivanovich Bakhmutov
, 
Mikhail Victorovich Galakhov 1
Mikhail Victorovich Galakhov
1 A. N. Nesmeyanov Institute of Organoelement Compounds, USSR Academy of Sciences, Moscow
10.1070/RC1988v057n09ABEH003394
Published 30 November 1987
Communication , Volume 57, Issue 9, 839-851
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Bakhmutov V. I., Galakhov M. V. NMR Spectroscopy of Polyfluorinated Allyl Cations // Russian Chemical Reviews. 1988. Vol. 57. No. 9. pp. 839-851.
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Bakhmutov V. I., Galakhov M. V. NMR Spectroscopy of Polyfluorinated Allyl Cations // Russian Chemical Reviews. 1988. Vol. 57. No. 9. pp. 839-851.
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TY - JOUR
DO - 10.1070/RC1988v057n09ABEH003394
UR - https://rcr.colab.ws/publications/10.1070/RC1988v057n09ABEH003394
TI - NMR Spectroscopy of Polyfluorinated Allyl Cations
T2 - Russian Chemical Reviews
AU - Bakhmutov, Vladimir Ivanovich
AU - Galakhov, Mikhail Victorovich
PY - 1988
DA - 1987/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 839-851
IS - 9
VL - 57
ER -
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@article{1988_Bakhmutov,
author = {Vladimir Ivanovich Bakhmutov and Mikhail Victorovich Galakhov},
title = {NMR Spectroscopy of Polyfluorinated Allyl Cations},
journal = {Russian Chemical Reviews},
year = {1988},
volume = {57},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1988v057n09ABEH003394},
number = {9},
pages = {839--851},
doi = {10.1070/RC1988v057n09ABEH003394}
}
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Bakhmutov, Vladimir Ivanovich, and Mikhail Victorovich Galakhov. “NMR Spectroscopy of Polyfluorinated Allyl Cations.” Russian Chemical Reviews, vol. 57, no. 9, Nov. 1988, pp. 839-851. https://rcr.colab.ws/publications/10.1070/RC1988v057n09ABEH003394.
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Abstract

The results of the NMR study of the hydrocarbon allyl cations are briefly surveyed. The 13C and 19F NMR spectra of polyfluorinated cyclic and acyclic allyl cations are considered and the spectral features of their formation in solutions are discussed. The influence of substituents and of the positive charge on the chemical shifts and the spin–spin coupling constants 1J(13C–19F) and 4J(19F–19F) of polyfluorinated allyl cations are considered. NMR data are presented on the relative stabilities of polyfluorinated allyl cations.
The bibliography includes 85 references.