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The mechanism of the partial oxidation of methane

Mikhail Yur'evich Sinev 1
Mikhail Yur'evich Sinev
, 
Vladimir Nikolaevich Korshak 1
Vladimir Nikolaevich Korshak
, 
Oleg Valentinovich Krylov 1
Oleg Valentinovich Krylov
1 Institute of Chemical Physics of the USSR Academy of Sciences, Moscow
Published 30 November 1988
Communication , Volume 58, Issue 1, 22-34
26
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Sinev M. Y., Korshak V. N., Krylov O. V. The mechanism of the partial oxidation of methane // Russian Chemical Reviews. 1989. Vol. 58. No. 1. pp. 22-34.
GOST all authors (up to 50)
Sinev M. Y., Korshak V. N., Krylov O. V. The mechanism of the partial oxidation of methane // Russian Chemical Reviews. 1989. Vol. 58. No. 1. pp. 22-34.
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TY - JOUR
DO - 10.1070/RC1989v058n01ABEH003423
UR - https://rcr.colab.ws/publications/10.1070/RC1989v058n01ABEH003423
TI - The mechanism of the partial oxidation of methane
T2 - Russian Chemical Reviews
AU - Sinev, Mikhail Yur'evich
AU - Korshak, Vladimir Nikolaevich
AU - Krylov, Oleg Valentinovich
PY - 1989
DA - 1988/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 22-34
IS - 1
VL - 58
ER -
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@article{1989_Sinev,
author = {Mikhail Yur'evich Sinev and Vladimir Nikolaevich Korshak and Oleg Valentinovich Krylov},
title = {The mechanism of the partial oxidation of methane},
journal = {Russian Chemical Reviews},
year = {1989},
volume = {58},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1989v058n01ABEH003423},
number = {1},
pages = {22--34},
doi = {10.1070/RC1989v058n01ABEH003423}
}
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Sinev, Mikhail Yur'evich, et al. “The mechanism of the partial oxidation of methane.” Russian Chemical Reviews, vol. 58, no. 1, Nov. 1989, pp. 22-34. https://rcr.colab.ws/publications/10.1070/RC1989v058n01ABEH003423.
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Abstract

The principal characteristics of the homogeneous and heterogeneous-catalytic conversion of methane into condensation products (C2 and C3 hydrocarbons) and partial oxidation products (methanol and formaldehyde) are considered. Data are presented concerning the most effective catalysts and data relating to the mechanism of the activation of methane on oxide and oxide halide catalysts, the nature of the active centres, and the kinetics of the partial oxidation of methane are analysed. It is shown that the oxidative condensation of methane in the presence of the catalysts considered is a heterogeneous-homogeneous process, which imposes special requirements in its practical realisation.
The bibliography includes 118 references.