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Catalytic decomposition of organic and organoelemental peroxides in the presence of electron donors and electron acceptors

Nina Vladimirovna Yablokova 1
Nina Vladimirovna Yablokova
, 
Yurii Arsent'evich Aleksandrov 1
Yurii Arsent'evich Aleksandrov
1 Chemistry Research Institute of N. I. Lobachevsky, State University of Gor'kii
10.1070/RC1989v058n06ABEH003458
Published 30 November 1988
Communication , Volume 58, Issue 6, 534-543
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Yablokova N. V., Aleksandrov Y. A. Catalytic decomposition of organic and organoelemental peroxides in the presence of electron donors and electron acceptors // Russian Chemical Reviews. 1989. Vol. 58. No. 6. pp. 534-543.
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Yablokova N. V., Aleksandrov Y. A. Catalytic decomposition of organic and organoelemental peroxides in the presence of electron donors and electron acceptors // Russian Chemical Reviews. 1989. Vol. 58. No. 6. pp. 534-543.
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TY - JOUR
DO - 10.1070/RC1989v058n06ABEH003458
UR - https://rcr.colab.ws/publications/10.1070/RC1989v058n06ABEH003458
TI - Catalytic decomposition of organic and organoelemental peroxides in the presence of electron donors and electron acceptors
T2 - Russian Chemical Reviews
AU - Yablokova, Nina Vladimirovna
AU - Aleksandrov, Yurii Arsent'evich
PY - 1989
DA - 1988/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 534-543
IS - 6
VL - 58
ER -
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@article{1989_Yablokova,
author = {Nina Vladimirovna Yablokova and Yurii Arsent'evich Aleksandrov},
title = {Catalytic decomposition of organic and organoelemental peroxides in the presence of electron donors and electron acceptors},
journal = {Russian Chemical Reviews},
year = {1989},
volume = {58},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1989v058n06ABEH003458},
number = {6},
pages = {534--543},
doi = {10.1070/RC1989v058n06ABEH003458}
}
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Yablokova, Nina Vladimirovna, and Yurii Arsent'evich Aleksandrov. “Catalytic decomposition of organic and organoelemental peroxides in the presence of electron donors and electron acceptors.” Russian Chemical Reviews, vol. 58, no. 6, Nov. 1989, pp. 534-543. https://rcr.colab.ws/publications/10.1070/RC1989v058n06ABEH003458.
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Abstract

The main characteristics (the kinetics and mechanism) of the radical decomposition of organic and organoelemental peroxides in the presence of active electron-donor and electron-acceptor components in alkanes and polymerising media are discussed. The decisive role of the formation of complexes of peroxides with active catalytic components and olefins in these processes is shown. The formation of triple complexes of monomer–Lewis acid–olefin plays an important part in the initiation of radical polymerisation. Examples of the practical application of the initiating systems peroxide–electron donor and peroxide–electron acceptor are given.
The bibliography includes 122 references.