Home / Articles / Present ideas on the influence of the medium on acid–base equilibria. Hydrogen bonds in the gas phase and in solution

Present ideas on the influence of the medium on acid–base equilibria. Hydrogen bonds in the gas phase and in solution

Lina Meerovna Epshtein 1
Lina Meerovna Epshtein
, 
A V Iogansen 2
A V Iogansen
1 A. N. Nesmeyanov Institute of Organoelement Compounds, USSR Academy of Sciences, Moscow
2 State Research and Design Institute of Nitrogen Industry, Moscow
10.1070/RC1990v059n02ABEH003515
Published 30 November 1989
Communication , Volume 59, Issue 2, 134-151
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Epshtein L. M., Iogansen A. V. Present ideas on the influence of the medium on acid–base equilibria. Hydrogen bonds in the gas phase and in solution // Russian Chemical Reviews. 1990. Vol. 59. No. 2. pp. 134-151.
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Epshtein L. M., Iogansen A. V. Present ideas on the influence of the medium on acid–base equilibria. Hydrogen bonds in the gas phase and in solution // Russian Chemical Reviews. 1990. Vol. 59. No. 2. pp. 134-151.
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TY - JOUR
DO - 10.1070/RC1990v059n02ABEH003515
UR - https://rcr.colab.ws/publications/10.1070/RC1990v059n02ABEH003515
TI - Present ideas on the influence of the medium on acid–base equilibria. Hydrogen bonds in the gas phase and in solution
T2 - Russian Chemical Reviews
AU - Epshtein, Lina Meerovna
AU - Iogansen, A V
PY - 1990
DA - 1989/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 134-151
IS - 2
VL - 59
ER -
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@article{1990_Epshtein,
author = {Lina Meerovna Epshtein and A V Iogansen},
title = {Present ideas on the influence of the medium on acid–base equilibria. Hydrogen bonds in the gas phase and in solution},
journal = {Russian Chemical Reviews},
year = {1990},
volume = {59},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1990v059n02ABEH003515},
number = {2},
pages = {134--151},
doi = {10.1070/RC1990v059n02ABEH003515}
}
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Epshtein, Lina Meerovna, and A V Iogansen. “Present ideas on the influence of the medium on acid–base equilibria. Hydrogen bonds in the gas phase and in solution.” Russian Chemical Reviews, vol. 59, no. 2, Nov. 1990, pp. 134-151. https://rcr.colab.ws/publications/10.1070/RC1990v059n02ABEH003515.
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Abstract

Data on acid–base equilibria in different media and in the gas phase have been analysed. Methods for determining the protonation centre in a gas have been discussed. The change in the electronic effects of substituents on going from the gas phase to solution have been examined. The relationships between the strength of ionic hydrogen bonds and the acid–base properties of compounds in the gas phase have been demonstrated, and the results obtained by modelling solvation effects in the gas phase have been examined. New data on the structure and stability of molecular H-complexes in the gas phase and on the increase in the strength of the H-bond on solvation are presented.
The bibliography contains 130 references.