Home / Articles / Catalysis by metal complexes in organoaluminium synthesis

Catalysis by metal complexes in organoaluminium synthesis

Usein Memetovich Dzhemilev ¹

Usein Memetovich Dzhemilev

0000-0002-7992-6337

Ol'ga Sergeevna Vostrikova ¹

Ol'ga Sergeevna Vostrikova

Genrikh Alexandrovich Tolstikov ¹

Genrikh Alexandrovich Tolstikov

¹ Institute of Chemistry of the Bashkir Scientific Center, Ural Branch of the USSR, Ufa

10.1070/RC1990v059n12ABEH003584

Copy DOI

Published 30 November 1989

Communication , Volume 59, Issue 12, 1157-1173

View PDF

1990, Volume 59, Issue 12

1 December 1990

Cite this

GOST

Cite this

GOST

Copy cite

Dzhemilev U. M., Vostrikova O. S., Tolstikov G. A. Catalysis by metal complexes in organoaluminium synthesis // Russian Chemical Reviews. 1990. Vol. 59. No. 12. pp. 1157-1173.

GOST all authors (up to 50)

Copy cite

Dzhemilev U. M., Vostrikova O. S., Tolstikov G. A. Catalysis by metal complexes in organoaluminium synthesis // Russian Chemical Reviews. 1990. Vol. 59. No. 12. pp. 1157-1173.

RIS

Cite this

RIS

Copy cite

TY - JOUR

DO - 10.1070/RC1990v059n12ABEH003584

UR - https://rcr.colab.ws/publications/10.1070/RC1990v059n12ABEH003584

TI - Catalysis by metal complexes in organoaluminium synthesis

T2 - Russian Chemical Reviews

AU - Dzhemilev, Usein Memetovich

AU - Vostrikova, Ol'ga Sergeevna

AU - Tolstikov, Genrikh Alexandrovich

PY - 1990

DA - 1989/11/30

PB - ANO Editorial Board of the journal Uspekhi Khimii

SP - 1157-1173

IS - 12

VL - 59

ER -

BibTex

Cite this

BibTex (up to 50 authors)

Copy cite

@article{1990_Dzhemilev,

author = {Usein Memetovich Dzhemilev and Ol'ga Sergeevna Vostrikova and Genrikh Alexandrovich Tolstikov},

title = {Catalysis by metal complexes in organoaluminium synthesis},

journal = {Russian Chemical Reviews},

year = {1990},

volume = {59},

publisher = {ANO Editorial Board of the journal Uspekhi Khimii},

month = {Nov},

url = {https://rcr.colab.ws/publications/10.1070/RC1990v059n12ABEH003584},

number = {12},

pages = {1157--1173},

doi = {10.1070/RC1990v059n12ABEH003584}

}

MLA

Cite this

MLA

Copy cite

Dzhemilev, Usein Memetovich, et al. “Catalysis by metal complexes in organoaluminium synthesis.” Russian Chemical Reviews, vol. 59, no. 12, Nov. 1990, pp. 1157-1173. https://rcr.colab.ws/publications/10.1070/RC1990v059n12ABEH003584.

Views / Visits / Downloads

13 / 13 / 5

Abstract

In this review a summary is given of studies conducted both within and outside the Soviet Union on the synthesis and conversions of organoaluminium compounds (OACs) in the presence of metal complexes as catalysts. The following reactions have been examined: catalytic hydro-, carbo- and cyclo-alumination of unsaturated compounds, cross-coupling and conjugate addition of OACs to enones, and certain other conversions of OACs in the presence of metal complexes as catalysts.
The bibliography includes 211 references.

References

A. A. Krasnovskii

Dokl. Akad. Nauk SSSR , 1948

A. A. Krasnovskii

Zhur. Fiz. Khim. , 1956

M. F. Shostakovskii

"Prostye Vinilovye Efiry" (Vinyl Ethers) , 1952

A. A. Krasnovskii

Dokl. Akad. Nauk SSSR , 1949

10.1021/jo01338a025

Hydrometalation. 3. Hydroalumination of alkenes and dienes catalyzed by transition metal halides

Ashby E.C., Noding S.A.

Journal of Organic Chemistry , 1979

10.1021/jo00407a004

Selective reduction of alkenes and alkynes by the reagent lithium aluminum hydride-transition-metal halide

Ashby E.C., Lin J.J.

Journal of Organic Chemistry , 1978

10.1021/jo01294a023

Hydrometalation. 5. Hydroalumination of alkenes and alkynes with complex metal hydrides of aluminum in the presence of bis(cyclopentadienyl)dichlorotitanium

Ashby E.C., Noding S.A.

Journal of Organic Chemistry , 1980

V. N. Kondrat'ev

"Kinetika Reaktsii v Gazovoi Faze" (Kinetics of Reactions in the Gas Phase) , 1959

10.1016/S0022-328X(00)88688-X

Nickel-catalyzed hydralumination of alkynes and the nickel effect in the ziegler dimerization of ethylene

Eisch J.J., Foxton M.W.

Journal of Organometallic Chemistry , 1968

10.

T. A. Kryukova

"Polyaro-graficheskii Analiz" (Polarographic Analysis) , 1959

11.

T. T. Bannister

Diss. Abstr. , 1959

12.

V. B. Evstigneev

Dokl. Akad. Nauk SSSR , 1950

13.

10.1351/pac198153122333

Bimetallic catalytic systems containing Ti, Zr, Ni, and Pd. Their applications to selective organic syntheses

Negishi E.

Pure and Applied Chemistry , 1981

14.

10.1021/ja00406a071

Mechanism of the zirconium-catalyzed carboalumination of alkynes. Evidence for direct carboalumination

Yoshida T., Negishi E.

Journal of the American Chemical Society , 1981

15.

10.1021/ic50099a006

Animoalanes. Direct synthesis from aluminum, hydrogen, and secondary amines. Structure and stability elucidation by nuclear magnetic resonance, infrared spectra, and differential thermal and thermal gravimetric analysis

Ashby E.C., Kovar R.A.

Inorganic Chemistry , 1971

16.

10.1016/S0040-4039(01)83573-5

Hydrometallation of alkenes and alkynes by bis-diisopropylaminoalane catalyzed by Cp2TiCl2

Ashby E.C., Noding S.A.

Tetrahedron Letters , 1977

17.

10.1016/S0022-328X(00)92336-2

Hydrometallation : IV. Hydroalumination of alkynes by hai(NR2)2 compounds catalyzed by Cp2TiCl2

Ashby E.C., Noding S.R.

Journal of Organometallic Chemistry , 1979

18.

10.1016/S0040-4039(00)71310-4

Reduction of alkynes and monosubstituted alkenes with lithium aluminum hydride and titanium tetrachloride

Chum P.W., Wilson S.E.

Tetrahedron Letters , 1976

19.

A. A. Krasnovskii

Dokl. Akad. Nauk SSSR , 1954

20.

A. A. Krasnovskii

Dokl. Akad. Nauk SSSR , 1958

21.

A. A. Krasnovskii

Dokl. Akad. Nauk SSSR , 1958

22.

10.1016/S0022-328X(00)80622-1

Addition of lithium aluminium hydride to olefins catalyzed by zirconium tetrachloride: A convenient route to alkanes and 1-haloalkanes from 1-alkenes

Sato F., Sato S., Sato M.

Journal of Organometallic Chemistry , 1976

23.

10.1016/S0022-328X(00)91817-5

Reactions of lithium aluminum hydride or alane with olefins catalyzed by titanium tetrachloride or zirconium tetrachloride. a convenient route to alkanes, 1-haloalkanes and terminal alcohols from alkenes

Sato F., Sato S., Kodama H., Sato M.

Journal of Organometallic Chemistry , 1977

24.

10.1016/S0040-4039(01)95514-5

Hydroalumination of olefins catalyzed by immobilized titanium compounds

Sato F., Ishikawa H., Takahashi Y., Miura M., Sato M.

Tetrahedron Letters , 1979

25.

B. Ya. Dain

1957

26.

A. A. Krasnovskii

Biofizika , 1956

27.

10.1016/S0022-328X(00)99589-5

Hydroalumination of olefins by the LiAlH4/UCl4 system

Le Marechal J., Ephritikhine M., Folcher G.

Journal of Organometallic Chemistry , 1986

28.

10.1246/cl.1980.103

DEALUMINOXYLATION OF ALUMINUM ALLYL OR BENZYL ALKOXIDES AND DEOXYGENATION OF ALLYL ETHERS BY LITHIUM ALUMINUM HYDRIDE IN THE PRESENCE OF TITANIUM CATALYST

Sato F., Tomuro Y., Ishikawa H., Oikawa T., Sato M.

Chemistry Letters , 1980

29.

10.1016/S0022-328X(00)82126-9

Mixed-metal hydride complexes containing ZrHA1 bridges. synthesis and relation to transition-metal-catalyzed reactions of aluminum hydrides

Shoer L.I., Gell K.I., Schwartz J.

Journal of Organometallic Chemistry , 1977

30.

10.1246/cl.1977.975

A SIMPLE SYNTHESIS OF 1-OCTEN-3-OL(MATSUTAKE ALCOHOL) BY THE TITANIUM-CATALYZED HIGHLY SELECTIVE REDUCTION OF THE BUTADIENE TELOMER WITH LiAlH₄

Tsuji J., Mandai T.

Chemistry Letters , 1977

31.

10.1016/S0040-4039(01)85333-8

Application of allylpalladium intermediate to a simple stereoselective synthesis of (±)-1-hydroxy-trans-8-dodecenoic acid, a precursor of naturally occurring macrolide from cephalosporium recifei

Tsuji J., Yamakawa T., Mandai T.

Tetrahedron Letters , 1978

32.

10.1246/cl.1978.833

REACTIONS OF ORGANOALUMINUMS WITH COPPER(II) HALIDES. A CONVENIENT ROUTE TO ALKYL HALIDES PROM OLEFINS VIA HYDROALUMINATION

Sato F., Mori Y., Sato M.

Chemistry Letters , 1978

33.

10.1016/S0022-328X(00)93419-3

Reactions of Lithium Aluminum Hydride with Nonconjugated diolefins. Selective reductions of diolefins and selective preparations of haloolefins from diolefins

Sato F., Sato S., Sato M.

Journal of Organometallic Chemistry , 1977

34.

10.1016/S0040-4039(00)98985-8

Application de reactions d'hydroalumination en synthese organique: obtention d'α-alkyl α-hydroxyesters par addition enantioselective de tetraalkylaluminates AU phenylglyoxalate de (−) menthyle.

Boireau G., Korenova A., Deberly A., Abenhaïm D.

Tetrahedron Letters , 1985

35.

10.1016/S0022-328X(00)92296-4

Application of hydroalumination reactions in organic syntheses. coupling reactions of organoaluminum compounds with allylic halides catalyzed by copper compounds

Sato F., Kodama H., Sato M.

Journal of Organometallic Chemistry , 1978

36.

L. M. Kosobutskaya

Dokl. Akad. Nauk SSSR , 1950

37.

10.1246/cl.1979.167

ADDITION OF ORGANOALUMINATES TO ACROLEIN OR METHYL VINYL KETONE IN THE PRESENCE OF A STOICHIOMETRIC AMOUNT OF COPPER(II) ACETATE. A CONVENIENT ROUTE TO KETONES AND ALDEHYDES FROM OLEFINS VIA HYDROALUMINATION

Sato F., Oikawa T., Sato M.

Chemistry Letters , 1979

38.

10.1246/cl.1978.1155

ALKYL–ALKYL COUPLING OF LITHIUM ALKYLALUMINATES AND ALKYL–ALLYL CROSS-COUPLING OF THE ALUMINATES WITH ALLYLIC HALIDES BY THE USE OF COPPER (II) ACETATE: AN APPLICATION OF THE CATALYTIC HYDROALUMINATION OF OLEFINS TO ORGANIC SYNTHESIS

Isagawa K., Ohige M., Tatsumi K., Otsuji Y.

Chemistry Letters , 1978

39.

10.1246/cl.1978.789

A CONVENIENT ROUTE FROM 1-ALKENES TO TERMINAL ACETYLENES VIA HYDROALUMINATION REACTIONS

Sato F., Kodama H., Sato M.

Chemistry Letters , 1978

40.

10.1246/cl.1977.1117

PREPARATION OF ALCOHOLS VIA HYDROALUMINATION OF OLEFINS BY USE OF THE Cp₂TiCl₂–LiAlH₄REAGENT SYSTEM

Isagawa K., Tatsumi K., Otsuji Y.

Chemistry Letters , 1977

41.

10.1016/S0040-4039(01)86162-1

Department of Chemical Engineering, Tokyo Institute of Technology, Meguro, Tokyo 152, Japan

Sato F., Mori Y., Sato M.

Tetrahedron Letters , 1979

42.

10.1070/RC1986v055n02ABEH003172

Zirconium Complexes in Synthesis and Catalysis

Dzhemilev U.M., Vostrikova O.S., Ibragimov A.G.

Russian Chemical Reviews , 1986

43.

W. Hendrich

Roczniki Chemii , 1958

44.

V. B. Evstigneev

Dokl. Akad. Nauk SSSR , 1955

45.

G. Oster

"Research in Photosynthesis" , 1957

46.

A. A. Krasnovskii

Dokl. Akad. Nauk SSSR , 1955

47.

A. A. Krasnovskii

Biofizika , 1958

48.

10.1016/S0040-4039(00)92757-6

A novel zirconium-catalyzed hydroalumination of olefins

Negishi E., Yoshida T.

Tetrahedron Letters , 1980

49.

A. A. Krasnovskii

Dokl. Akad. Nauk SSSR , 1954

50.

V. B. Evstigneev

Dokl. Akad. Nauk SSSR , 1957

51.

D. Porretand E. Rabinowitch

Nature , 1937

52.

R. Livingston

J. Phys. Chem. , 1941

53.

G. A. Bogdanovskii

1958

54.

10.1515/znb-1984-0804

Über die katalytische Umwandlung von Olefinen, VIII „Nacktes“ Nickel als Katalysator bei der Umalkylierung von Aluminiumtrialkylen mit α-Olefinen/ The Catalytic Conversion of Olefins, VIII „Naked“-Nickel as a Catalyst for the Transalkylation of Aluminium Trialkyls with α-Olefins

Fischer K., Jonas K., Mollbach A., Wilke G.

Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences , 1984

55.

10.1016/0040-4039(81)80021-4

Nickel-catalyzed stereodifferentiating displacement reaction between prochiral 1-alkenes and optically active organoaluminium solvates.

Giacomelli G., Bertero L., Lardicci L.

Tetrahedron Letters , 1981

56.

10.1016/0022-328X(90)85232-N

Organometallic compounds of group III. XLIV: Molecular hydrogen and aluminum hydride transfers mediated by nickel(0) complexes; the intermediacy of nickel hydrides in the Ziegler nickel effect

Eisch J.J., Sexsmith S.R., Fichter K.C.

Journal of Organometallic Chemistry , 1990

57.

10.1021/jo01316a016

Metal catalysis in organic reactions. 7. The role of nickel complexes in the reaction of triisobutylaluminum with terminal acetylenes

Giacomelli G., Caporusso A.M., Lardicci L.

Journal of Organic Chemistry , 1979

58.

A. N. Terenin

Optika i Spektrosk. , 1956

59.

10.1021/jo00425a038

Metal catalysis in organic reactions. 3. Nickel-promoted reaction of triisobutylaluminum with terminal acetylenes as a synthetic route to (E)-2,4-dialkyl-1,3-butadienes and/or trialkylbenzenes

Caporusso A.M., Giacomelli G., Lardicci L.

Journal of Organic Chemistry , 1977

60.

10.1021/jo01323a028

Metal catalysis in organic reactions. 8. Alkylative dimerization of 1-alkynes induced by tris(acetylacetonato)manganese/trialkylalane systems

Caporusso A.M., Giacomelli G., Lardicci L.

Journal of Organic Chemistry , 1979

61.

1930

62.

Chem. Zentr. II , 1931

63.

10.1021/jo00317a032

Synthesis of (Z)-4-methylhex-3-en-1-ol via the reaction of 3-hexyn-1-ol with trimethylaluminum-titanium tetrachloride

Schiavelli M.D., Plunkett J.J., Thompson D.W.

Journal of Organic Chemistry , 1981

64.

10.1021/jo00212a024

Transition metal promoted alkylations of unsaturated alcohols: the selective methylation of homopropargyl alcohols via titanium tetrachloride-trimethylaluminum

Ewing J.C., Ferguson G.S., Moore D.W., Schultz F.W., Thompson D.W.

Journal of Organic Chemistry , 1985

65.

10.1021/jo00172a068

A facile and selective methylation of 5-en-3-yn-1-ols with titanium tetrachloride-trimethylaluminum yielding (3Z)-4-methylalka-3,5-dien-1-ols

Zitzelberger T.J., Schiavelli M.D., Thompson D.W.

Journal of Organic Chemistry , 1983

66.

10.1021/jo00445a036

Alkylations of alkynols with organoaluminum reagents promoted by bis(.eta.5-cyclopentadienyl)titanium dichloride

Smedley L.C., Tweedy H.E., Coleman R.A., Thompson D.W.

Journal of Organic Chemistry , 1977

67.

10.1021/jo01334a002

Transition metal promoted alkylations of unsaturated alcohols. Alkylation of alkynols with organoalanes promoted by Group IVA metal-cyclopentadienyl compounds

Brown D.C., Nichols S.A., Gilpin A.B., Thompson D.W.

Journal of Organic Chemistry , 1979

68.

10.1016/S0022-328X(00)88748-3

Transition metal promoted alkylations of unsaturated alcohols: the methylation and ethylation of 3-buten-1-ol using titanium tetrachloride-organoaluminum systems

Youngblood A.V., Nichols S.A., Coleman R.A., Thompson D.W.

Journal of Organometallic Chemistry , 1978

69.

10.1016/S0022-328X(00)84891-3

Controlled carbometallation : II. The addition reaction of trimethylalane-titanocene dichloride with acetylenes

Van Horn D.E., Valente L.F., Idacavage M.J., Negishi E.

Journal of Organometallic Chemistry , 1978

70.

10.1016/S0022-328X(00)92232-0

Regiospecific and stereoselective carbometallation of alkynylsilanes by Ziegler-Natta alkylating agents

Eisch J.J., Manfre R.J., Komar D.A.

Journal of Organometallic Chemistry , 1978

71.

10.1016/S0022-328X(00)91752-2

Stereocontrolled carbotitanation of alkynylsilanes

Snider B.B., Karras M.

Journal of Organometallic Chemistry , 1979

72.

10.1021/ja00424a071

Attack by phosphorus nucleophiles on a cluster-bound vinyl group. The crystal structure of HOs3(CO)10(CHCH2PMe2Ph)

Churchill M.R., DeBoer B.G., Shapley J.R., Keister J.B.

Journal of the American Chemical Society , 1976

73.

10.1021/ja00509a078

Reaction of alkynes with a methylnickel complex: observation of a cis insertion mechanism capable of giving kinetically controlled trans products

Huggins J.M., Bergman R.G.

Journal of the American Chemical Society , 1979

74.

10.1021/ja00475a058

Selective carbon-carbon bond formation via transition metal catalysts. 8. Controlled carbometalation. Reaction of acetylenes with organoalane-zirconocene dichloride complexes as a route to stereo- and regio-defined trisubstituted olefins

Van Horn D.E., Negishi E.

Journal of the American Chemical Society , 1978

75.

10.1021/ar00134a004

Controlled carbometalation as a new tool for carbon-carbon bond formation and its application to cyclization

Negishi E.

Accounts of Chemical Research , 1987

76.

A. A. Krasnovskii

Dokl. Akad. Nauk SSSR , 1949

77.

10.1016/S0022-328X(00)99674-8

Homogeneous zirconium based catalysts in organic synthesis

Dzhemilev U.M., Vostrikova O.S., Tolstikov G.A.

Journal of Organometallic Chemistry , 1986

78.

10.1055/s-1988-27453

Organozirconium Compounds in Organic Synthesis

Negishi E., Takahashi T.

Synthesis , 1988

79.

10.1021/ja00309a036

Controlled carbometalation. 20. Carbometalation reaction of alkynes with organoalene-zirconocene derivatives as a route to stereo-and regiodefined trisubstituted alkenes

Negishi E., Van Horn D.E., Yoshida T.

Journal of the American Chemical Society , 1985

80.

10.1016/S0040-4039(01)94778-1

Synthesis of prostaglandin I3 (PGI3)

Nidy E.G., Johnson R.A.

Tetrahedron Letters , 1978

81.

10.1055/s-1980-29313

A Selective and Efficient Synthesis of (E)-4-Methyl-3-alken-1-ols via Zirconium-Catalyzed Carboalumination of Terminal Alkynes

Kobayashi M., Valente L.F., Negishi E., Patterson W., Silveira, Jr. A.

Synthesis , 1980

82.

10.1021/jo00333a041

A versatile and selective route to difunctional trisubstituted (E)-alkene synthons via zirconium-catalyzed carboalumination of alkynes

Rand C.L., Van Horn D.E., Moore M.W., Negishi E.

Journal of Organic Chemistry , 1981

83.

10.1246/cl.1985.1409

CARBOMETALLATION OF 1,4-BIS(TRIMETHYLSILYL)-1,3-BUTADIYNE WITH TRIMETHYLALUMINIUM

Kusumoto T., Nishide K., Hiyama T.

Chemistry Letters , 1985

84.

10.1021/ja00358a043

Novel silicon-promoted cycloalkylation of alkenylmetal derivatives

Negishi E., Boardman L.D., Tour J.M., Sawada H., Rand C.L.

Journal of the American Chemical Society , 1983

85.

10.1021/ja00332a072

Metal promoted cyclization. 5. Mechanistic duality in cyclialkylation of alkenylmetal derivatives

Boardman L.D., Bagheri V., Sawada H., Negishi E.

Journal of the American Chemical Society , 1984

86.

10.1021/ja00224a025

Metal promoted cyclization. 18. Novel cyclialkylation reactions of (.omega.-halo-1-alkenyl)metal derivatives. Synthetic scope and mechanism

Negishi E., Boardman L.D., Sawada H., Bagheri V., Stoll A.T., Tour J.M., Rand C.L.

Journal of the American Chemical Society , 1988

87.

10.1246/cl.1982.293

CARBOALUMINATION OF ALKYNES WITH DIALKYLCHLOROALANES IN THE PRESENCE OF ZIRCONOCENE DICHLORIDE. AN IMPROVED METHOD FOR CARBOALUMINATION OF ALKYNES

Yoshida T.

Chemistry Letters , 1982

88.

10.1016/S0040-4039(01)91032-9

Reaction of alkenes and dienes with t-butylmagnesium halides and zirconocene dihalides. A convenient procedure for hydrozirconation and a novel t-butylzirconation of conjugated alkenes

Negishi E., Miller J.A., Yoshida T.

Tetrahedron Letters , 1984

89.

10.1021/jo00371a036

A selective method for the synthesis of stereodefined exocyclic alkenes via allylmetalation of propargyl alcohols

Negishi E., Zhang Y., Cederbaum F.E., Webb M.B.

Journal of Organic Chemistry , 1986

90.

10.1002/ijch.198400013

Cyclic Carboalumination of Alkynylsilanes Forming Exocyclic Alkenes

Miller J.A., Negishi E.

Israel Journal of Chemistry , 1984

91.

10.1016/S0040-4039(00)94511-8

Synthesis of trichoverrol B

Roush W.R., Spada A.P.

Tetrahedron Letters , 1983

92.

10.1021/ja00541a045

Stereoselective synthesis of brassinolide: a plant growth promoting steroidal lactone

Fung S., Siddall J.B.

Journal of the American Chemical Society , 1980

93.

10.1021/ja00381a049

Total synthesis of milbemycin .beta.3

Williams D.R., Barner B.A., Nishitani K., Phillips J.G.

Journal of the American Chemical Society , 1982

94.

10.1021/jo00153a035

Synthesis of verrucarin J

Roush W.R., Blizzard T.A.

Journal of Organic Chemistry , 1983

95.

10.1021/jo00149a021

Activation parameters for thiolate-disulfide interchange reactions in aqueous solution

Whitesides G.M., Houk J., Patterson M.A.

Journal of Organic Chemistry , 1983

96.

10.1021/jo00184a021

Synthesis of epoxytrichothecenes: verrucarin J and verrucarin J isomers

Roush W.R., Blizzard T.A.

Journal of Organic Chemistry , 1984

97.

10.1021/jo00197a002

Synthesis of verrucarin B

Roush W.R., Blizzard T.A.

Journal of Organic Chemistry , 1984

98.

10.1016/S0040-4020(01)91129-9

Synthesis of naturally occurring brassinosteroids employing cleavage of 23,34-epoxides as key reactions. Synthesis of brassinolide, castasterone, dolicholide, dolichosterone, homodolicholide, homodolichosterone, 6-deoxocastasterone and 6-deoxodolichosterone

Mori K., Sakakibara M., Okada K.

Tetrahedron , 1984

99.

10.1039/p19850001589

A total synthesis of zoapatanol

Cookson R.C., Liverton N.J.

Journal of the Chemical Society Perkin Transactions 1 , 1985

100.

10.1016/S0040-4020(01)81102-9

Studies in marine cembranolide synthesis: A synthesis of 2,3,5-trisubstituted furan intermediates for lophotoxin and pukalide

Paterson I., Mark G., Banks B.J.

Tetrahedron , 1989

101.

10.1039/c39860001237

Enantiospecific synthesis of the C-9 to C-18 fragment of macbecins I and II

Baker R., Cummings W.J., Hayes J.F., Kumar A.

Journal of the Chemical Society Chemical Communications , 1986

102.

10.1039/p19870002189

The 3,4-dihydro-2H-pyran approach to (+)-milbemycin β₃. Part 2. An improved synthesis of (2R,4S,6S,8R,9S)-2-[(5R)-(2E)-3-methyl-5-formyl-hex-2-en-1-yl]-8,9-dimethyl-4-(dimethyl-t-butylsilyloxy)-1,7-dioxaspiro[5.5]undecane

Kocieński P.J., Street S.D., Yeates C., Cambell S.F.

Journal of the Chemical Society Perkin Transactions 1 , 1987

103.

10.1016/0304-5102(78)80030-3

The insertion of 3-buten-1-OL into metal—alkyl bonds utilizing typical titanium—aluminum ziegler—natta catalysts

Tweedy H.E., Hahn P.E., Smedley L.C., Youngblood A.V., Coleman R.A., Thompson D.W.

Journal of Molecular Catalysis , 1978

104.

10.1021/ja00479a061

Olefin homologation with titanium methylene compounds

Tebbe F.N., Parshall G.W., Reddy G.S.

Journal of the American Chemical Society , 1978

105.

109

F. Ficher

Bull. Soc. chim. France (4) , 1916

106.

110

M. F. Shostakovskii

Dokl. Akad. Nauk SSSR , 1960

107.

111

M. Calvin

1956

108.

10.1021/jo01334a042

Conversion of monoalkyl olefins to 1,1-dialkyl olefins by reaction with bis(cyclopentadienyl)titanium dichloride-trialkylaluminum

Barber J.J., Willis C., Whitesides G.M.

Journal of Organic Chemistry , 1979

109.

113

H. Blum

"Photodynamic Action and Diseases caused Light" , 1940

110.

114

L. Segal

"Chemical Reactions of Polymers" , 1964

111.

10.1016/0022-328X(85)87355-1

Some novelties in olefin carbometallation assisted by alkyl-magnesium and -aluminium derivatives and catalyzed by zirconium and titanium complexes

Dzhemilev U.M., Vostrikova O.S.

Journal of Organometallic Chemistry , 1985

112.

116

V. B. Evstigneev

Dokl. Akad. Nauk SSSR , 1957

113.

117

V. V. Levchenko

Zhur. Obshch. Khim. , 1948

114.

10.1016/0277-5387(82)80001-6

The preparation and properties of metallacyclic compounds of the transition elements

Chappell S.D., Cole-Hamilton D.J.

Polyhedron , 1982

115.

119

V. V. Levchenko

Zhur. Obshch. Khim. , 1947

116.

120

V. V. Levchenko

Zhur. Obshch. Khim. , 1948

117.

121

V. V. Korshak

Izv. Akad. Nauk SSSR, Otd. Khim. Nauk , 1953

118.

122

S. R. Rafikov

Izv. Akad. Nauk SSSR, Otd. Khim. Nauk , 1953

119.

123

V. V. Levchenko

Zhur. Obshch. Khim. , 1952

120.

124

V. V. Levchenko

Zhur. Obshch. Khim. , 1952

121.

125

K. A. Andrianov

Vysokomol. Soed. , 1960

122.

126

J. Wiemannand Ch. Clachet

Compt. rend. , 1948

123.

127

R. Pasternak

Helv. Chim. Acta , 1948

124.

128

J. Wiemann

Bull. Soc. chim. France , 1952

125.

129

J. Wiemann

Bull. Soc. chim. France , 1955

126.

130

J. Wiemann

Bull. Soc. chim. France , 1958

127.

131

N. Thooi

Compt. rend. , 1958

128.

132

G. Shima

Kyoto Univ. , 1929

129.

133

C. Wilson

Trans. Electrochem. Soc. , 1941

130.

134

V. V. Korshak

Izv. Akad. Nauk SSSR, Otd. Khim. Nauk , 1948

131.

135

V. V. Korshak

Dokl. Akad. Nauk SSSR , 1945

132.

136

V. V. Korshak

Izv. Akad. Nauk SSSR, Otd. Khim. Nauk , 1954

133.

137

S. R. Rafikov

Zh. Obshch. Khim. , 1944

134.

138

S. Ono

J. Chem. Soc. Japan , 1957

135.

139

I. L. Knunyants

1959

136.

10.1021/ja00437a067

A novel stereospecific alkenyl-alkenyl cross-coupling by a palladium- or nickel-catalyzed reaction of alkenylalanes with alkenyl halides

Baba S., Negishi E.

Journal of the American Chemical Society , 1976

137.

141

Friedl.

138.

10.1021/jo00157a044

Selective carbon-carbon bond formation via transition-metal catalysis. 33. Palladium-catalyzed cross-coupling reaction of .alpha.-heterosubstituted alkenylmetals. A stereoselective route to heterosubstituted dienes suitable for the Diels-Alder reaction

Negishi E., Luo F.

Journal of Organic Chemistry , 1983

139.

10.1016/S0040-4039(01)90533-7

Highly selective synthesis of allylated arenes and diarylmethanes via palladium-catalyzed cross coupling involving benzylic derivatives

Negishi E., Matsushita H., Okukado N.

Tetrahedron Letters , 1981

140.

10.1055/s-1987-28084

A Single-Step Synthesis of Tamoxifen Using Palladium-Catalyzed Cross-Coupling

AI-Hassan M.I.

Synthesis , 1987

141.

10.1016/0022-328X(87)80330-3

Synthesis of broparestrol using palladium-catalyzed cross-coupling

Al-Hassan M.I.

Journal of Organometallic Chemistry , 1987

142.

10.1080/00397918708057766

Palladium-Catalyzed Cross-Coupling of Vinylalanes with Aryl Halides

Al-hassan M.I.

Synthetic Communications , 1987

143.

10.1016/S0040-4020(01)89506-5

Palladium-catalyzed diastereoselective syntheses of (E)-1-trimethylsilyl-2-alkenes, (E)-1-trimethylsilyl-1-alken-3-ynes, (1E,5E)-1-trimethylsilyl-1,5-alkadien-3-ynes, (1E,3Z)- and (1E,3E)-1-trimethylsilyl- 1,3-alkadienes

Andreini B.P., Carpita A., Rossi R., Scamuzzi B.

Tetrahedron , 1989

144.

10.1021/ja00242a024

Nickel- or palladium-catalyzed cross coupling. 31. Palladium- or nickel-catalyzed reactions of alkenylmetals with unsaturated organic halides as a selective route to arylated alkenes and conjugated dienes: scope, limitations, and mechanism

Negishi E., Takahashi T., Baba S., Van Horn D.E., Okukado N.

Journal of the American Chemical Society , 1987

145.

10.1021/ja00475a059

Selective carbon-carbon bond formation via transition metal catalysts. 9. Double metal catalysis in the cross-coupling reaction and its application to the stereo- and regioselective synthesis of trisubstituted olefins

Negishi E., Okukado N., King A.O., Van Horn D.E., Spiegel B.I.

Journal of the American Chemical Society , 1978

146.

10.1016/S0040-4020(01)86901-5

Highly stereo- and regioselective palladium-catalyzed syntheses of (3E,Z)-,(3E,5E)-, and (3Z,5E)-1,3,5-undecatriene

Andreini B.P., Benetti M., Carpita A., Rossi R.

Tetrahedron , 1987

147.

10.1016/S0040-4039(00)95383-8

Selective palladium-catalysed substitution of 1,1-dichloroethylene

Ratovelomanana V., Hammoud A., Linstrumelle G.

Tetrahedron Letters , 1987

148.

10.1039/c39820000160

anti-Stereospecificity in the palladium-catalysed reactions of alkenyl- or aryl-metal derivatives with allylic electrophiles

Matsushita H., Negishi E.

Journal of the Chemical Society Chemical Communications , 1982

149.

10.1021/ja00400a074

Selective carbon-carbon bond formation via transition-metal catalysis. Part 18. Palladium-catalyzed stereo- and regiospecific coupling of allylic derivatives with alkenyl- and arylmetals. A highly selective synthesis and 1,4-dienes

Matsushita H., Negishi E.

Journal of the American Chemical Society , 1981

150.

10.1055/s-1974-23393

Allylation of Vinylalanes. A Convenient Synthesis of Isomerically Puretrans-1,4-Dienes

LYND R.A., ZWEIFEL G.

Synthesis , 1974

151.

10.1016/S0040-4039(01)82007-4

Scope of the palladium-catalyzed coupling reaction of organometallics with allylic electrophiles. Effect of the leaving group☆

Negishi E., Chatterjee S., Matsushita H.

Tetrahedron Letters , 1981

152.

156

J. S. Fruton

J. Biol. Med. , 1950

153.

157

1903

154.

10.1016/S0040-4039(00)94960-8

Ketone synthesis via palladium-catalyzed carbonylation of organoaluminium compounds

Bumagin N.A., Ponomaryov A.B., Beletskaya I.P.

Tetrahedron Letters , 1985

155.

159

J. Tafel

Z. Elektrochem. , 1911

156.

10.1246/bcsj.54.1281

Ketone Synthesis from Acid Chloride by Means of Organometallic Reagent Derived from R₃Al–Cu(acac)₂-PPh₃System

Takai K., Oshima K., Nozaki H.

Bulletin of the Chemical Society of Japan , 1981

157.

161

Friedl.

158.

162

1917

159.

10.1016/0022-328X(85)87328-9

Cross-coupling reactions between some allyl, homoallyl, and homopropargyl substrates and trialkylalanes or dialkyl- and diaryl-magnesium derivatives *

Tolstikov G.A., Dzhemilev U.M.

Journal of Organometallic Chemistry , 1985

160.

164

1917

161.

165

Friedl.

162.

166

1917

163.

167

Friedl.

164.

10.1246/cl.1978.805

APPLICATION OF HYDROALUMINATION REACTIONS IN ORGANIC SYNTHESES. A CONVENIENT ROUTE TO TERMINAL ALLENES FROM 1-OLEFINS

Sato F., Oguro K., Sato M.

Chemistry Letters , 1978

165.

171

Friedl.

166.

172

1918

167.

173

Friedl.

168.

174

S. Calvert

India Rubber Tire Rev. , 1926

169.

175

I. Mayer

1966

170.

176

G. V. Samsonov

"Metody Ispytaniya na Mikrotverdost' i Pribory" (Methods of Microhardness Testing and Apparatus) , 1965

171.

10.1016/0022-328X(85)87358-7

A new method for the synthesis of vinyl- and di-allenes assisted by organoaluminium compounds

Tolstikov G.A., Romanova T.Y., Kuchin A.V.

Journal of Organometallic Chemistry , 1985

172.

178

1946

173.

179

Chem. Abs. , 1947

174.

180

1946

175.

181

Chem. Abs. , 1947

176.

10.1071/CH9750801

Nickel-catalysed conjugate addition of trimethylaluminium to α,β-unsaturated ketones

Bagnell L., Jeffery E., Meisters A., Mole T.

Australian Journal of Chemistry , 1975

177.

10.1071/CH9750817

Nickel-catalysed conjugate addition of trimethylaluminium to 3-Oxo-Δ4-steroids

Bagnell L., Meisters A., Mole T.

Australian Journal of Chemistry , 1975

178.

10.1021/jo00936a035

Transition metal catalyzed conjugated methylation of .alpha.,.beta.-unsaturated detones by trimethyl aluminum and lithium tetramethylaluminate

Ashby E.C., Heinsohn G.

Journal of Organic Chemistry , 1974

179.

10.1021/jo01303a024

Nickel-catalyzed conjugate addition of alkynyl groups to .alpha.,.beta.-unsaturated ketones

Schwartz J., Carr D.B., Hansen R.T., Dayrit F.M.

Journal of Organic Chemistry , 1980

180.

10.1021/ja00475a052

Nickel-catalyzed conjugate addition of organoaluminum acetylides to .alpha.,.beta.-enones

Hansen R.T., Carr D.B., Schwartz J.

Journal of the American Chemical Society , 1978

181.

187

1954

182.

10.1021/jo00354a027

Methylcopper(I)-catalyzed selective conjugate reduction of .alpha.,.beta.-unsaturated carbonyl compounds by di-iso-butylaluminum hydride in the presence of hexamethylphosphoric triamide

Tsuda T., Hayashi T., Satomi H., Kawamoto T., Saegusa T.

Journal of Organic Chemistry , 1986

183.

10.1021/jo00145a007

Metal catalysis in organic reactions. 16. Conjugate reduction of .alpha.,.beta.-unsaturated ketones by trialkylalane-nickel systems

Caporusso A.M., Giacomelli G., Lardicci L.

Journal of Organic Chemistry , 1982

184.

10.1246/bcsj.58.2425

Palladium-catalyzed Ketone Synthesis from Acyl Chloride and Organoaluminum Reagents

Wakamatsu K., Okuda Y., Oshima K., Nozaki H.

Bulletin of the Chemical Society of Japan , 1985

185.

10.1002/jlac.198819880617

Copper(I) iodide-promoted reaction of some electrophiles with the aluminium enolate generated by the stereoselective conjugate reduction of (7as)-(+)-5,6,7,7a-tetrahydro-7a-methylindan-1,5-dione

Daniewski A.R., Kiegiel J., Piotrowska E., Warchoł T., Wojciechowska W.

1988

186.

10.1021/ja00539a033

Titanacyclobutenes

Tebbe F.N., Harlow R.L.

Journal of the American Chemical Society , 1980

187.

10.1016/S0040-4039(01)81672-5

The methylenation of enolizable ketones and esters using organotitanium chemistry

Clawson L., Buchwald S.L., Grubbs R.H.

Tetrahedron Letters , 1984

188.

10.1016/S0040-4039(00)85429-5

Identifizierung und synthese von periplanon A

Hauptmann H., Mühlbauer G., Sass H.

Tetrahedron Letters , 1986

189.

10.1021/ja00529a076

Titanium-mediated methylene-transfer reactions. Direct conversion of esters into vinyl ethers

Pine S.H., Zahler R., Evans D.A., Grubbs R.H.

Journal of the American Chemical Society , 1980

190.

10.1016/S0040-4039(00)81873-0

Non-wittig type reaction of tebbe reagent with acyl chloride☆

chou T., Huang S.

Tetrahedron Letters , 1983

191.

10.1016/S0040-4039(01)91550-3

Transition-metal catalyzed silylmetalation of allenes

Morizawa Y., Oda H., Oshima K., Nozaki H.

Tetrahedron Letters , 1984

192.

10.1016/S0040-4039(01)81185-0

Regioselective stannylmetalation of acetylenes in the presence of transition-metal catalyst

Hibino J., Matsubara S., Morizawa Y., Oshima K., Nozaki H.

Tetrahedron Letters , 1984

193.

10.1016/0022-328X(85)87365-4

Regio- and stereo-selective synthesis of vinylstannanes. Transition-metal catalyzed stannylmetalation of acetylenes and conversion of enol triflates and vinyl iodides into vinylstannanes

Matsubara S., Hibino J., Morizawa Y., Oshima K., Nozaki H.

Journal of Organometallic Chemistry , 1985

194.

10.1016/S0040-4039(00)85422-2

Control of regiochemistry in bismetallation of 1-decyne

Sharma S., Ochlschlager A.C.

Tetrahedron Letters , 1986

195.

10.1021/jo00282a021

Scope and mechanism of stannylalumination of 1-alkynes

Sharma S., Oehlschlager A.C.

Journal of Organic Chemistry , 1989

196.

10.1246/bcsj.58.1196

Synthesis of Homoallylic Alcohols from Allylic Phosphates and Aldehydes with Organoaluminum Reagent Containing Al–Sn Linkage

Matsubara S., Wakamatsu K., Morizawa Y., Tsuboniwa N., Oshima K., Nozaki H.

Bulletin of the Chemical Society of Japan , 1985

197.

10.1021/ja00351a071

Tris(trimethylsilyl)aluminum and transition-metal catalysts. Silylation of allyl acetates

Trost B.M., Yoshida J., Lautens M.

Journal of the American Chemical Society , 1983

198.

206

J. Petersen

Z. Phys. Chem. , 1900

199.

207

F. Fichter

"Organische Elektrochemie" , 1942

200.

208

O. A. Reutov

"Teoreticheskie Problemy Organicheskoi Khimii" (Theoretical Problems in Organic Chemistry) , 1956

201.

10.1071/CH9742577

A new conversion of nitriles into acetyl compounds: Nickel-catalysed methylation by trimethylaluminium

Bagnell L., Jeffery E., Meisters A., Mole T.

Australian Journal of Chemistry , 1974

202.

10.1021/jo00142a031

Palladium-catalyzed reactions of allylic electrophiles with organometallic reagents. A regioselective 1,4-elimination and a regio- and stereoselective reduction of allylic derivatives

Matsushita H., Negishi E.

Journal of Organic Chemistry , 1982

203.

211

C. Schall

Z. Elektrochem. , 1923

204.

212

L. V. Pavlova

Zh. Obshch. Khim. , 1965

205.

213

F. Yu. Rachinskii

"Khimiya Seraorganicheskikh Soedinenii, Soderzhashchikh-sya v Neftyakh i Nefteproduktakh" (Chemistry of Organo-sulphur Compounds Present in Petroleum and Petroleum Products) , 1966

206.

214

L. V. Pavlova

1965

207.

215

N. D. Tomashov

Zh. Prikl. Khim. , 1970

208.

216

A. P. Tomilov

Zhur. Prikl. Khim. , 1959

209.

217

1925

210.

218

Chem. Zentr. II , 1925

211.

219

G. I. Pustoshkin

Collected Papers "Biologicheskie Aktivnie Soedinenii" (Biologically Active Compounds) , 1955

212.

220

K. Ziegler

Angew. Chem. , 1955

213.

221

1960

214.

222

Chem. Abs. , 1961