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Electron phototransfer in the initiation of polymerisation

Marina Nikolaevna Usacheva 1
Marina Nikolaevna Usacheva
, 
Iosif Iosifovich Dilung 1
Iosif Iosifovich Dilung
1 L. V. Pisarzhevskii Institute of Physical Chemistry, Academy of Sciences of Ukraine, Kiev
10.1070/RC1991v060n01ABEH001034
Published 30 November 1990
Communication , Volume 60, Issue 1, 106-121
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Usacheva M. N., Dilung I. I. Electron phototransfer in the initiation of polymerisation // Russian Chemical Reviews. 1991. Vol. 60. No. 1. pp. 106-121.
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Usacheva M. N., Dilung I. I. Electron phototransfer in the initiation of polymerisation // Russian Chemical Reviews. 1991. Vol. 60. No. 1. pp. 106-121.
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TY - JOUR
DO - 10.1070/RC1991v060n01ABEH001034
UR - https://rcr.colab.ws/publications/10.1070/RC1991v060n01ABEH001034
TI - Electron phototransfer in the initiation of polymerisation
T2 - Russian Chemical Reviews
AU - Usacheva, Marina Nikolaevna
AU - Dilung, Iosif Iosifovich
PY - 1991
DA - 1990/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 106-121
IS - 1
VL - 60
ER -
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@article{1991_Usacheva,
author = {Marina Nikolaevna Usacheva and Iosif Iosifovich Dilung},
title = {Electron phototransfer in the initiation of polymerisation},
journal = {Russian Chemical Reviews},
year = {1991},
volume = {60},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1991v060n01ABEH001034},
number = {1},
pages = {106--121},
doi = {10.1070/RC1991v060n01ABEH001034}
}
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Usacheva, Marina Nikolaevna, and Iosif Iosifovich Dilung. “Electron phototransfer in the initiation of polymerisation.” Russian Chemical Reviews, vol. 60, no. 1, Nov. 1991, pp. 106-121. https://rcr.colab.ws/publications/10.1070/RC1991v060n01ABEH001034.
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Abstract

The results of studies on the participation of exciplexes and other products of electron phototransfer in the initiation of polymerisation are correlated in the review. The relationship between the nature of the primary radical species and the mechanism of initiation of a polymerisation chain is discussed. Particular attention is given to the effect of the electronic structure of the photoinitiator, the chemical nature of the activator and monomer, and the polarity of the medium on the mechanism of photoinitiation and its efficiency. The bibliography includes 165 references.