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Asymmetric epoxidation

Yurii Efimovich Raifel'd 1
Yurii Efimovich Raifel'd
, 
A M Vaisman 1
A M Vaisman
1 M. V. Lomonosov Moscow Institute of Fine Chemical Technology
10.1070/RC1991v060n02ABEH001035
Published 30 November 1990
Communication , Volume 60, Issue 2, 123-145
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Raifel'd Y. E., Vaisman A. M. Asymmetric epoxidation // Russian Chemical Reviews. 1991. Vol. 60. No. 2. pp. 123-145.
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Raifel'd Y. E., Vaisman A. M. Asymmetric epoxidation // Russian Chemical Reviews. 1991. Vol. 60. No. 2. pp. 123-145.
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TY - JOUR
DO - 10.1070/RC1991v060n02ABEH001035
UR - https://rcr.colab.ws/publications/10.1070/RC1991v060n02ABEH001035
TI - Asymmetric epoxidation
T2 - Russian Chemical Reviews
AU - Raifel'd, Yurii Efimovich
AU - Vaisman, A M
PY - 1991
DA - 1990/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 123-145
IS - 2
VL - 60
ER -
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@article{1991_Raifel'd,
author = {Yurii Efimovich Raifel'd and A M Vaisman},
title = {Asymmetric epoxidation},
journal = {Russian Chemical Reviews},
year = {1991},
volume = {60},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1991v060n02ABEH001035},
number = {2},
pages = {123--145},
doi = {10.1070/RC1991v060n02ABEH001035}
}
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Raifel'd, Yurii Efimovich, and A M Vaisman. “Asymmetric epoxidation.” Russian Chemical Reviews, vol. 60, no. 2, Nov. 1991, pp. 123-145. https://rcr.colab.ws/publications/10.1070/RC1991v060n02ABEH001035.
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Abstract

The data on asymmetric epoxidation that have been obtained in recent years are correlated. Particular attention is given to the epoxidation of allylic alcohols with Sharpless reagent, which is a chiral complex of a titanium alkoxide with dialkyl tartrate. The structure of the catalyst, a model of the transition state, and the reaction mechanism are examined. The bibliography includes 242 references.