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Norbornadiene–quadricyclane – an effective molecular system for the storage of solar energy

Vladimir Aleksandrovich Bren 1
Vladimir Aleksandrovich Bren
, 
Alexander Dmitrievich Dubonosov 1
Alexander Dmitrievich Dubonosov
,  , 
Vladimir Alekseevich Chernoivanov 1
Vladimir Alekseevich Chernoivanov
1 Institute of Physical and Organic Chemistry at Rostov State University
10.1070/RC1991v060n05ABEH001088
Published 30 November 1990
Communication , Volume 60, Issue 5, 451-469
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Bren V. A. et al. Norbornadiene–quadricyclane – an effective molecular system for the storage of solar energy // Russian Chemical Reviews. 1991. Vol. 60. No. 5. pp. 451-469.
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Bren V. A., Dubonosov A. D., Minkin V. I., Chernoivanov V. A. Norbornadiene–quadricyclane – an effective molecular system for the storage of solar energy // Russian Chemical Reviews. 1991. Vol. 60. No. 5. pp. 451-469.
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TY - JOUR
DO - 10.1070/RC1991v060n05ABEH001088
UR - https://rcr.colab.ws/publications/10.1070/RC1991v060n05ABEH001088
TI - Norbornadiene–quadricyclane – an effective molecular system for the storage of solar energy
T2 - Russian Chemical Reviews
AU - Bren, Vladimir Aleksandrovich
AU - Dubonosov, Alexander Dmitrievich
AU - Minkin, Vladimir Isaakovich
AU - Chernoivanov, Vladimir Alekseevich
PY - 1991
DA - 1990/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 451-469
IS - 5
VL - 60
ER -
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@article{1991_Bren,
author = {Vladimir Aleksandrovich Bren and Alexander Dmitrievich Dubonosov and Vladimir Isaakovich Minkin and Vladimir Alekseevich Chernoivanov},
title = {Norbornadiene–quadricyclane – an effective molecular system for the storage of solar energy},
journal = {Russian Chemical Reviews},
year = {1991},
volume = {60},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1991v060n05ABEH001088},
number = {5},
pages = {451--469},
doi = {10.1070/RC1991v060n05ABEH001088}
}
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Bren, Vladimir Aleksandrovich, et al. “Norbornadiene–quadricyclane – an effective molecular system for the storage of solar energy.” Russian Chemical Reviews, vol. 60, no. 5, Nov. 1991, pp. 451-469. https://rcr.colab.ws/publications/10.1070/RC1991v060n05ABEH001088.
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Abstract

The results of studies on intramolecular interconversions in systems of norbornadiene ⇄ quadricyclane and their derivatives are classified and discussed. The mechanisms of the forward photoreaction and reverse thermal process in relation to the nature of the substituents and carbocycles, type of sensitiser and catalyst, and properties of the medium are discussed in detail and classified. An analysis is made of the influence of these factors on the spectroscopic, kinetic, and thermodynamic properties of this system as an accumulator and converter of light energy. Methods of improving its characteristics – light absorption, the quantum yield of the photoreaction, and stability of the photoproduct – have been established. The bibliography includes 188 references.