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Kinetics and mechanism of the oxidation of organic compounds with hydrogen peroxide

Vladimir Nikolaevich Kislenko 1
Vladimir Nikolaevich Kislenko
, 
Adol'f Abramovich Berlin 1
Adol'f Abramovich Berlin
1 L'vov Polytechnical Institute
Published 30 November 1990
Communication , Volume 60, Issue 5, 470-488
21
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Kislenko V. N., Berlin A. A. Kinetics and mechanism of the oxidation of organic compounds with hydrogen peroxide // Russian Chemical Reviews. 1991. Vol. 60. No. 5. pp. 470-488.
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Kislenko V. N., Berlin A. A. Kinetics and mechanism of the oxidation of organic compounds with hydrogen peroxide // Russian Chemical Reviews. 1991. Vol. 60. No. 5. pp. 470-488.
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RIS
TY - JOUR
DO - 10.1070/RC1991v060n05ABEH001089
UR - https://rcr.colab.ws/publications/10.1070/RC1991v060n05ABEH001089
TI - Kinetics and mechanism of the oxidation of organic compounds with hydrogen peroxide
T2 - Russian Chemical Reviews
AU - Kislenko, Vladimir Nikolaevich
AU - Berlin, Adol'f Abramovich
PY - 1991
DA - 1990/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 470-488
IS - 5
VL - 60
ER -
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@article{1991_Kislenko,
author = {Vladimir Nikolaevich Kislenko and Adol'f Abramovich Berlin},
title = {Kinetics and mechanism of the oxidation of organic compounds with hydrogen peroxide},
journal = {Russian Chemical Reviews},
year = {1991},
volume = {60},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1991v060n05ABEH001089},
number = {5},
pages = {470--488},
doi = {10.1070/RC1991v060n05ABEH001089}
}
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Kislenko, Vladimir Nikolaevich, and Adol'f Abramovich Berlin. “Kinetics and mechanism of the oxidation of organic compounds with hydrogen peroxide.” Russian Chemical Reviews, vol. 60, no. 5, Nov. 1991, pp. 470-488. https://rcr.colab.ws/publications/10.1070/RC1991v060n05ABEH001089.
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Abstract

The literature data on the kinetics and mechanism of the oxidation of organic compounds of various nature with hydrogen peroxide in aqueous solution have been analysed. A generalised kinetic scheme is described for the radical–chain decomposition of hydrogen peroxide in the presence of organic compounds for which a rate equation for the process has been found by the method of quasi-steady-state concentrations for long chains. Partial expressions have been obtained for the rate of oxidation of various organic compounds with hydrogen peroxide allowing for the nature of the organic compound. The bibliography contains 85 references.