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From sandwich and triple-decker to organometallic polymers

Walter Siebert 1
Walter Siebert
1 University of Heidelberg, Germany
10.1070/RC1991v060n07ABEH001110
Published 30 November 1990
Communication , Volume 60, Issue 7, 784-791
31
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Siebert W. From sandwich and triple-decker to organometallic polymers // Russian Chemical Reviews. 1991. Vol. 60. No. 7. pp. 784-791.
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Siebert W. From sandwich and triple-decker to organometallic polymers // Russian Chemical Reviews. 1991. Vol. 60. No. 7. pp. 784-791.
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TY - JOUR
DO - 10.1070/RC1991v060n07ABEH001110
UR - https://rcr.colab.ws/publications/10.1070/RC1991v060n07ABEH001110
TI - From sandwich and triple-decker to organometallic polymers
T2 - Russian Chemical Reviews
AU - Siebert, Walter
PY - 1991
DA - 1990/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 784-791
IS - 7
VL - 60
ER -
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@article{1991_Siebert,
author = {Walter Siebert},
title = {From sandwich and triple-decker to organometallic polymers},
journal = {Russian Chemical Reviews},
year = {1991},
volume = {60},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1991v060n07ABEH001110},
number = {7},
pages = {784--791},
doi = {10.1070/RC1991v060n07ABEH001110}
}
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Siebert, Walter. “From sandwich and triple-decker to organometallic polymers.” Russian Chemical Reviews, vol. 60, no. 7, Nov. 1991, pp. 784-791. https://rcr.colab.ws/publications/10.1070/RC1991v060n07ABEH001110.
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Abstract

Several types of organometallic polymers with different backbones are known. Our approach for the construction of metal-containing polymers uses the ability of Lewis-acidic boron heterocycles to interact antifacially with metals. The boron heterocycle 2,3-dihydro-1,3-diborole not only allows the formation of sandwich and triple-decker complexes but also the stacking of metal complex fragments to oligodecker and polydecker compounds. This account reviews sandwich and triple-decker complexes as potential building blocks for polymers. The bibliography includes 46 references.