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Mechanism of heterogeneous oxidation of acrolein to acrylic acid

Tamara Vital'evna Andrushkevich 1
Tamara Vital'evna Andrushkevich
, 
Galina Yakovlevna Popova 1
Galina Yakovlevna Popova
1 Institute of Catalysis Siberian Branch of the Russian Academy of Sciences, Novosibirsk
Published 30 November 1990
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Andrushkevich T. V., Popova G. Y. Mechanism of heterogeneous oxidation of acrolein to acrylic acid // Russian Chemical Reviews. 1991. Vol. 60. No. 9. pp. 1023-1034.
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Andrushkevich T. V., Popova G. Y. Mechanism of heterogeneous oxidation of acrolein to acrylic acid // Russian Chemical Reviews. 1991. Vol. 60. No. 9. pp. 1023-1034.
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TY - JOUR
DO - 10.1070/RC1991v060n09ABEH001126
UR - https://rcr.colab.ws/publications/10.1070/RC1991v060n09ABEH001126
TI - Mechanism of heterogeneous oxidation of acrolein to acrylic acid
T2 - Russian Chemical Reviews
AU - Andrushkevich, Tamara Vital'evna
AU - Popova, Galina Yakovlevna
PY - 1991
DA - 1990/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 1023-1034
IS - 9
VL - 60
ER -
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BibTex (up to 50 authors)
@article{1991_Andrushkevich,
author = {Tamara Vital'evna Andrushkevich and Galina Yakovlevna Popova},
title = {Mechanism of heterogeneous oxidation of acrolein to acrylic acid},
journal = {Russian Chemical Reviews},
year = {1991},
volume = {60},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1991v060n09ABEH001126},
number = {9},
pages = {1023--1034},
doi = {10.1070/RC1991v060n09ABEH001126}
}
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MLA
Andrushkevich, Tamara Vital'evna, and Galina Yakovlevna Popova. “Mechanism of heterogeneous oxidation of acrolein to acrylic acid.” Russian Chemical Reviews, vol. 60, no. 9, Nov. 1991, pp. 1023-1034. https://rcr.colab.ws/publications/10.1070/RC1991v060n09ABEH001126.
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Abstract

A summary and analysis is given of results in the literature, and of our own results, of investigations into the mechanism of the heterogeneous oxidation of acrolein on oxide catalysts. The mechanism by which acrylic acid and oxides of carbon are formed from acrolein and oxygen is discussed. General principles for the interaction of acrolein with oxide catalysts are considered, and special attention is given to the nature of adsorption centres and the role of surface compounds of acrolein and acrylic acid, in the course of acrolein oxidation. On the basis of a proposed mechanism, some principles are formulated for the specific selection of catalysts for the selective oxidation of acrolein to acrylic acid. The bibliography includes 74 references.