Home / Articles / The verdazyl method for the study of the kinetics and mechanisms of the unimolecular heterolysis reactions of organic compounds

The verdazyl method for the study of the kinetics and mechanisms of the unimolecular heterolysis reactions of organic compounds

Genrikh Fedorovich Dvorko 1
Genrikh Fedorovich Dvorko
, 
Engel'sina Aleksandrovna Ponomareva 1
Engel'sina Aleksandrovna Ponomareva
1 Kiev Polytechnic Institute
10.1070/RC1991v060n10ABEH001130
Published 30 November 1990
Communication , Volume 60, Issue 10, 1071-1084
22
Share
Cite this
GOST
 | 
Cite this
GOST
Copy cite
Dvorko G. F., Ponomareva E. A. The verdazyl method for the study of the kinetics and mechanisms of the unimolecular heterolysis reactions of organic compounds // Russian Chemical Reviews. 1991. Vol. 60. No. 10. pp. 1071-1084.
GOST all authors (up to 50)
Copy cite
Dvorko G. F., Ponomareva E. A. The verdazyl method for the study of the kinetics and mechanisms of the unimolecular heterolysis reactions of organic compounds // Russian Chemical Reviews. 1991. Vol. 60. No. 10. pp. 1071-1084.
RIS
 | 
Cite this
RIS
Copy cite
TY - JOUR
DO - 10.1070/RC1991v060n10ABEH001130
UR - https://rcr.colab.ws/publications/10.1070/RC1991v060n10ABEH001130
TI - The verdazyl method for the study of the kinetics and mechanisms of the unimolecular heterolysis reactions of organic compounds
T2 - Russian Chemical Reviews
AU - Dvorko, Genrikh Fedorovich
AU - Ponomareva, Engel'sina Aleksandrovna
PY - 1991
DA - 1990/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 1071-1084
IS - 10
VL - 60
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors)
Copy cite
@article{1991_Dvorko,
author = {Genrikh Fedorovich Dvorko and Engel'sina Aleksandrovna Ponomareva},
title = {The verdazyl method for the study of the kinetics and mechanisms of the unimolecular heterolysis reactions of organic compounds},
journal = {Russian Chemical Reviews},
year = {1991},
volume = {60},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1991v060n10ABEH001130},
number = {10},
pages = {1071--1084},
doi = {10.1070/RC1991v060n10ABEH001130}
}
MLA
Cite this
MLA
Copy cite
Dvorko, Genrikh Fedorovich, and Engel'sina Aleksandrovna Ponomareva. “The verdazyl method for the study of the kinetics and mechanisms of the unimolecular heterolysis reactions of organic compounds.” Russian Chemical Reviews, vol. 60, no. 10, Nov. 1991, pp. 1071-1084. https://rcr.colab.ws/publications/10.1070/RC1991v060n10ABEH001130.
Views / Visits / Downloads
18 / 18 / 10

Abstract

Data concerning the use of triphenylverdazyl radicals as internal indicators to study the kinetics and mechanisms of the heterolysis of organic substrates in various protic and aprotic solvents are surveyed. The application of the verdazyl method made it possible to put forward a new mechanism of the heterolysis of a covalent bond – the reaction proceeds via the consecutive formation of contact, spatially separated, and solvent-separated ion pairs. The bibliography includes 135 references.