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Mechanism of the hydrogenolysis of thiophene on bimetallic sulfide catalysts

Anatolii Nikolaevich Startsev 1
Anatolii Nikolaevich Startsev
1 Institute of Catalysis SB RAS, Novosibirsk
10.1070/RC1992v061n02ABEH000939
Published 30 November 1991
Communication , Volume 61, Issue 2, 175-187
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Startsev A. N. Mechanism of the hydrogenolysis of thiophene on bimetallic sulfide catalysts // Russian Chemical Reviews. 1992. Vol. 61. No. 2. pp. 175-187.
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Startsev A. N. Mechanism of the hydrogenolysis of thiophene on bimetallic sulfide catalysts // Russian Chemical Reviews. 1992. Vol. 61. No. 2. pp. 175-187.
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TY - JOUR
DO - 10.1070/RC1992v061n02ABEH000939
UR - https://rcr.colab.ws/publications/10.1070/RC1992v061n02ABEH000939
TI - Mechanism of the hydrogenolysis of thiophene on bimetallic sulfide catalysts
T2 - Russian Chemical Reviews
AU - Startsev, Anatolii Nikolaevich
PY - 1992
DA - 1991/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 175-187
IS - 2
VL - 61
ER -
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@article{1992_Startsev,
author = {Anatolii Nikolaevich Startsev},
title = {Mechanism of the hydrogenolysis of thiophene on bimetallic sulfide catalysts},
journal = {Russian Chemical Reviews},
year = {1992},
volume = {61},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1992v061n02ABEH000939},
number = {2},
pages = {175--187},
doi = {10.1070/RC1992v061n02ABEH000939}
}
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Startsev, Anatolii Nikolaevich. “Mechanism of the hydrogenolysis of thiophene on bimetallic sulfide catalysts.” Russian Chemical Reviews, vol. 61, no. 2, Nov. 1992, pp. 175-187. https://rcr.colab.ws/publications/10.1070/RC1992v061n02ABEH000939.
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Abstract

The structure of the sulfide bimetallic species (SBMS), which is the active component of hydrodesulphurisation catalysts, is examined. The main principles of the hydrogenolysis of thiophene on well-characterised sulfide catalysts have been analysed. A synchronous mechanism for the reaction of thiophene with hydrogen in the coordination sphere is considered and substantiated. The bibliography includes 143 references.