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Retro-aldol processes in steroid chemistry

Mamed Khanguseinovich Dzhafarov 1
Mamed Khanguseinovich Dzhafarov
1 A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, Moscow
Published 30 November 1991
Communication , Volume 61, Issue 3, 363-372
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Dzhafarov M. K. Retro-aldol processes in steroid chemistry // Russian Chemical Reviews. 1992. Vol. 61. No. 3. pp. 363-372.
GOST all authors (up to 50)
Dzhafarov M. K. Retro-aldol processes in steroid chemistry // Russian Chemical Reviews. 1992. Vol. 61. No. 3. pp. 363-372.
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TY - JOUR
DO - 10.1070/RC1992v061n03ABEH000950
UR - https://rcr.colab.ws/publications/10.1070/RC1992v061n03ABEH000950
TI - Retro-aldol processes in steroid chemistry
T2 - Russian Chemical Reviews
AU - Dzhafarov, Mamed Khanguseinovich
PY - 1992
DA - 1991/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 363-372
IS - 3
VL - 61
ER -
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@article{1992_Dzhafarov,
author = {Mamed Khanguseinovich Dzhafarov},
title = {Retro-aldol processes in steroid chemistry},
journal = {Russian Chemical Reviews},
year = {1992},
volume = {61},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1992v061n03ABEH000950},
number = {3},
pages = {363--372},
doi = {10.1070/RC1992v061n03ABEH000950}
}
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Dzhafarov, Mamed Khanguseinovich. “Retro-aldol processes in steroid chemistry.” Russian Chemical Reviews, vol. 61, no. 3, Nov. 1992, pp. 363-372. https://rcr.colab.ws/publications/10.1070/RC1992v061n03ABEH000950.
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Abstract

This review is devoted to retro-aldol reactions in steroid chemistry. The mechanism of the two-centred inversion of the C/D ring junction is discussed, and its application to the synthesis of cardioaglycones (aglycones of cardioglycosides) outlined. Some stereochemical aspects of introducing a functionalised side chain at C17 is also examined. The bibliography includes 56 references.