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Inhibition–initiation in the pyrolysis of hydrocarbon mixtures

Lyudmila Vladimirovna Shevel'kova 1
Lyudmila Vladimirovna Shevel'kova
, 
Leonid Evgen'evich Gusel'nikov 1
Leonid Evgen'evich Gusel'nikov
, 
G Bach 2
G Bach
, 
G Zimmermann 2
G Zimmermann
1 A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow
2 Central Institute of Organic Chemistry, Germany
10.1070/RC1992v061n04ABEH000955
Published 30 November 1991
Communication , Volume 61, Issue 4, 433-445
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Shevel'kova L. V. et al. Inhibition–initiation in the pyrolysis of hydrocarbon mixtures // Russian Chemical Reviews. 1992. Vol. 61. No. 4. pp. 433-445.
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Shevel'kova L. V., Gusel'nikov L. E., Bach G., Zimmermann G. Inhibition–initiation in the pyrolysis of hydrocarbon mixtures // Russian Chemical Reviews. 1992. Vol. 61. No. 4. pp. 433-445.
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TY - JOUR
DO - 10.1070/RC1992v061n04ABEH000955
UR - https://rcr.colab.ws/publications/10.1070/RC1992v061n04ABEH000955
TI - Inhibition–initiation in the pyrolysis of hydrocarbon mixtures
T2 - Russian Chemical Reviews
AU - Shevel'kova, Lyudmila Vladimirovna
AU - Gusel'nikov, Leonid Evgen'evich
AU - Bach, G
AU - Zimmermann, G
PY - 1992
DA - 1991/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 433-445
IS - 4
VL - 61
ER -
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@article{1992_Shevel'kova,
author = {Lyudmila Vladimirovna Shevel'kova and Leonid Evgen'evich Gusel'nikov and G Bach and G Zimmermann},
title = {Inhibition–initiation in the pyrolysis of hydrocarbon mixtures},
journal = {Russian Chemical Reviews},
year = {1992},
volume = {61},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1992v061n04ABEH000955},
number = {4},
pages = {433--445},
doi = {10.1070/RC1992v061n04ABEH000955}
}
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Shevel'kova, Lyudmila Vladimirovna, et al. “Inhibition–initiation in the pyrolysis of hydrocarbon mixtures.” Russian Chemical Reviews, vol. 61, no. 4, Nov. 1992, pp. 433-445. https://rcr.colab.ws/publications/10.1070/RC1992v061n04ABEH000955.
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Abstract

The results of investigation on the mutual influence of hydrocarbons of various classes on the rate and route of decomposition under copyrolysis conditions are correlated and discussed. A general concept has been formulated as to the mechanism of the inhibition–initiation phenomenon based on competing chain propagation reactions according to which a hydrocarbon may act both as an inhibitor and as an initiator of decomposition. The course of this action is determined by the character of partner behaviour and by the concentration of reactive radicals. The bibliography contains 90 references.