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Stereoelectronic effects in silicon, phosphorus, and sulfur molecules. Quantum-chemical calculations and qualitative orbital models

A A Korkin 1
A A Korkin
1 Institute of Physiologically Active Compounds RAS, Chernogolovka
10.1070/RC1992v061n05ABEH000957
Published 30 November 1991
Communication , Volume 61, Issue 5, 473-483
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Korkin A. A. Stereoelectronic effects in silicon, phosphorus, and sulfur molecules. Quantum-chemical calculations and qualitative orbital models // Russian Chemical Reviews. 1992. Vol. 61. No. 5. pp. 473-483.
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Korkin A. A. Stereoelectronic effects in silicon, phosphorus, and sulfur molecules. Quantum-chemical calculations and qualitative orbital models // Russian Chemical Reviews. 1992. Vol. 61. No. 5. pp. 473-483.
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TY - JOUR
DO - 10.1070/RC1992v061n05ABEH000957
UR - https://rcr.colab.ws/publications/10.1070/RC1992v061n05ABEH000957
TI - Stereoelectronic effects in silicon, phosphorus, and sulfur molecules. Quantum-chemical calculations and qualitative orbital models
T2 - Russian Chemical Reviews
AU - Korkin, A A
PY - 1992
DA - 1991/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 473-483
IS - 5
VL - 61
ER -
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@article{1992_Korkin,
author = {A A Korkin},
title = {Stereoelectronic effects in silicon, phosphorus, and sulfur molecules. Quantum-chemical calculations and qualitative orbital models},
journal = {Russian Chemical Reviews},
year = {1992},
volume = {61},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1992v061n05ABEH000957},
number = {5},
pages = {473--483},
doi = {10.1070/RC1992v061n05ABEH000957}
}
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Korkin, A. A.. “Stereoelectronic effects in silicon, phosphorus, and sulfur molecules. Quantum-chemical calculations and qualitative orbital models.” Russian Chemical Reviews, vol. 61, no. 5, Nov. 1992, pp. 473-483. https://rcr.colab.ws/publications/10.1070/RC1992v061n05ABEH000957.
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Abstract

The results of non-empirical quantum-chemical calculations for silicon, phosphorus, and sulfur compounds of different structure are discussed. Qualitative orbital models, which establish a relation between the distribution of electrons and molecular structure and properties, are analysed. A general definition of stereoelectronic effects is presented. The bibliography includes 176 references.