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Conjunction in organic compounds of silicon-subgroup elements

Aleksei Nikolaevich Egorochkin 1
Aleksei Nikolaevich Egorochkin
1 Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhnii Novgorod
10.1070/RC1992v061n06ABEH000987
Published 30 November 1991
Communication , Volume 61, Issue 6, 600-612
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Egorochkin A. N. Conjunction in organic compounds of silicon-subgroup elements // Russian Chemical Reviews. 1992. Vol. 61. No. 6. pp. 600-612.
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Egorochkin A. N. Conjunction in organic compounds of silicon-subgroup elements // Russian Chemical Reviews. 1992. Vol. 61. No. 6. pp. 600-612.
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TY - JOUR
DO - 10.1070/RC1992v061n06ABEH000987
UR - https://rcr.colab.ws/publications/10.1070/RC1992v061n06ABEH000987
TI - Conjunction in organic compounds of silicon-subgroup elements
T2 - Russian Chemical Reviews
AU - Egorochkin, Aleksei Nikolaevich
PY - 1992
DA - 1991/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 600-612
IS - 6
VL - 61
ER -
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@article{1992_Egorochkin,
author = {Aleksei Nikolaevich Egorochkin},
title = {Conjunction in organic compounds of silicon-subgroup elements},
journal = {Russian Chemical Reviews},
year = {1992},
volume = {61},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1992v061n06ABEH000987},
number = {6},
pages = {600--612},
doi = {10.1070/RC1992v061n06ABEH000987}
}
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Egorochkin, Aleksei Nikolaevich. “Conjunction in organic compounds of silicon-subgroup elements.” Russian Chemical Reviews, vol. 61, no. 6, Nov. 1992, pp. 600-612. https://rcr.colab.ws/publications/10.1070/RC1992v061n06ABEH000987.
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Abstract

The existing theoretical ideas concerning the intramolecular interaction in organic compounds of silicon-subgroup elements are examined in relation to the results of experimental studies. It is shown that the overall resonance effect of organoelement substituents includes acceptor (joint influence of unoccupied nd and antibonding σ* orbitals) and donor (σ,π conjugation, σ,π* conjugation, and σ,n conjugation) components. The relative contributions of these components to the resonance effect are analysed as a function of the type of central element, the organic groups linked to it, and the reaction centre. The bibliography includes 161 references.