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The anomalous stabilisation of the oxidation state 2+ of lanthanides and actinides

Nikolai Borisovich Mikheev 1
Nikolai Borisovich Mikheev
, 
L N Auerman 1
L N Auerman
, 
Igor Andreevich Rumer 1
Igor Andreevich Rumer
, 
Alla Nikolaevna Kamenskaya 1
Alla Nikolaevna Kamenskaya
, 
Mikhail Zinov'evich Kazakevich 1
Mikhail Zinov'evich Kazakevich
1 Institute of Physical Chemistry, Russian Academy of Sciences, Moscow
10.1070/RC1992v061n10ABEH001011
Published 30 November 1991
Communication , Volume 61, Issue 10, 990-998
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Mikheev N. B. et al. The anomalous stabilisation of the oxidation state 2+ of lanthanides and actinides // Russian Chemical Reviews. 1992. Vol. 61. No. 10. pp. 990-998.
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Mikheev N. B., Auerman L. N., Rumer I. A., Kamenskaya A. N., Kazakevich M. Z. The anomalous stabilisation of the oxidation state 2+ of lanthanides and actinides // Russian Chemical Reviews. 1992. Vol. 61. No. 10. pp. 990-998.
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TY - JOUR
DO - 10.1070/RC1992v061n10ABEH001011
UR - https://rcr.colab.ws/publications/10.1070/RC1992v061n10ABEH001011
TI - The anomalous stabilisation of the oxidation state 2+ of lanthanides and actinides
T2 - Russian Chemical Reviews
AU - Mikheev, Nikolai Borisovich
AU - Auerman, L N
AU - Rumer, Igor Andreevich
AU - Kamenskaya, Alla Nikolaevna
AU - Kazakevich, Mikhail Zinov'evich
PY - 1992
DA - 1991/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 990-998
IS - 10
VL - 61
ER -
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@article{1992_Mikheev,
author = {Nikolai Borisovich Mikheev and L N Auerman and Igor Andreevich Rumer and Alla Nikolaevna Kamenskaya and Mikhail Zinov'evich Kazakevich},
title = {The anomalous stabilisation of the oxidation state 2+ of lanthanides and actinides},
journal = {Russian Chemical Reviews},
year = {1992},
volume = {61},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1992v061n10ABEH001011},
number = {10},
pages = {990--998},
doi = {10.1070/RC1992v061n10ABEH001011}
}
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Mikheev, Nikolai Borisovich, et al. “The anomalous stabilisation of the oxidation state 2+ of lanthanides and actinides.” Russian Chemical Reviews, vol. 61, no. 10, Nov. 1992, pp. 990-998. https://rcr.colab.ws/publications/10.1070/RC1992v061n10ABEH001011.
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Abstract

The present review deals with the anomalous stabilisation of the oxidation state 2+ of a number of lanthanides and actinides. This stabilisation of the oxidation state 2+ is due to the lowering of the energy of a d-orbital as a result of crystal field splitting in the ligand field and d-electron participation in chemical bonding.
The bibliography includes 68 references.