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Hydroxylation of aromatic compounds with nitrous oxide. New possibilities of oxidative catalysis on zeolites

Aleksandr Sergeevich Kharitonov 1
Aleksandr Sergeevich Kharitonov
,  , 
1 Boreskov Institute of Catalysis SB RAS, Novosibirsk
10.1070/RC1992v061n11ABEH001021
Published 30 November 1991
Communication , Volume 61, Issue 11, 1130-1139
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Kharitonov A. S., Sobolev V. I., Panov G. I. Hydroxylation of aromatic compounds with nitrous oxide. New possibilities of oxidative catalysis on zeolites // Russian Chemical Reviews. 1992. Vol. 61. No. 11. pp. 1130-1139.
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Kharitonov A. S., Sobolev V. I., Panov G. I. Hydroxylation of aromatic compounds with nitrous oxide. New possibilities of oxidative catalysis on zeolites // Russian Chemical Reviews. 1992. Vol. 61. No. 11. pp. 1130-1139.
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TY - JOUR
DO - 10.1070/RC1992v061n11ABEH001021
UR - https://rcr.colab.ws/publications/10.1070/RC1992v061n11ABEH001021
TI - Hydroxylation of aromatic compounds with nitrous oxide. New possibilities of oxidative catalysis on zeolites
T2 - Russian Chemical Reviews
AU - Kharitonov, Aleksandr Sergeevich
AU - Sobolev, Vladimir Ivanovich
AU - Panov, Gennadii Ivanovich
PY - 1992
DA - 1991/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 1130-1139
IS - 11
VL - 61
ER -
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@article{1992_Kharitonov,
author = {Aleksandr Sergeevich Kharitonov and Vladimir Ivanovich Sobolev and Gennadii Ivanovich Panov},
title = {Hydroxylation of aromatic compounds with nitrous oxide. New possibilities of oxidative catalysis on zeolites},
journal = {Russian Chemical Reviews},
year = {1992},
volume = {61},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1992v061n11ABEH001021},
number = {11},
pages = {1130--1139},
doi = {10.1070/RC1992v061n11ABEH001021}
}
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Kharitonov, Aleksandr Sergeevich, et al. “Hydroxylation of aromatic compounds with nitrous oxide. New possibilities of oxidative catalysis on zeolites.” Russian Chemical Reviews, vol. 61, no. 11, Nov. 1992, pp. 1130-1139. https://rcr.colab.ws/publications/10.1070/RC1992v061n11ABEH001021.
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Abstract

Studies on the use of zeolites in partial oxidation reactions are surveyed. Attention is concentrated on recent investigations of the gas-phase oxidative hydroxylation of aromatic compounds with nitrous oxide. Best results were achieved in the study of the simplest reaction of this type – the oxidation of benzene to phenol: in the presence of iron-containing ZSM-5 zeolites, the reaction proceeds with nearly 100% selectivity and a degree of conversion of benzene of 25–30%. Further development of this method for the introduction of hydroxy-groups may lead to new possibilities for the creation of effective technologies in the field of organic synthesis. The bibliography includes 87 references.