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Vibrational relaxation and vibrational predissociation as dynamic tunnelling processes

Evgenii Evgen'evich Nikitin 1
Evgenii Evgen'evich Nikitin
1 N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow
10.1070/RC1993v062n01ABEH000001
Published 30 November 1992
Communication , Volume 62, Issue 1, 1-10
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Nikitin E. E. Vibrational relaxation and vibrational predissociation as dynamic tunnelling processes // Russian Chemical Reviews. 1993. Vol. 62. No. 1. pp. 1-10.
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Nikitin E. E. Vibrational relaxation and vibrational predissociation as dynamic tunnelling processes // Russian Chemical Reviews. 1993. Vol. 62. No. 1. pp. 1-10.
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TY - JOUR
DO - 10.1070/RC1993v062n01ABEH000001
UR - https://rcr.colab.ws/publications/10.1070/RC1993v062n01ABEH000001
TI - Vibrational relaxation and vibrational predissociation as dynamic tunnelling processes
T2 - Russian Chemical Reviews
AU - Nikitin, Evgenii Evgen'evich
PY - 1993
DA - 1992/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 1-10
IS - 1
VL - 62
ER -
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@article{1993_Nikitin,
author = {Evgenii Evgen'evich Nikitin},
title = {Vibrational relaxation and vibrational predissociation as dynamic tunnelling processes},
journal = {Russian Chemical Reviews},
year = {1993},
volume = {62},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1993v062n01ABEH000001},
number = {1},
pages = {1--10},
doi = {10.1070/RC1993v062n01ABEH000001}
}
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Nikitin, Evgenii Evgen'evich. “Vibrational relaxation and vibrational predissociation as dynamic tunnelling processes.” Russian Chemical Reviews, vol. 62, no. 1, Nov. 1993, pp. 1-10. https://rcr.colab.ws/publications/10.1070/RC1993v062n01ABEH000001.
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Abstract

The dynamics of vibrational relaxation and vibrational predissociation processes, forbidden by the classical adiabatic Ehrenfest principle, are examined. A general approach to the calculation of rate constants for processes represented by total collision and half-collision models is formulated. Simple models which make it possible to understand the characteristics of the processes discussed are described and are extended to the case of real three-dimensional motion. Examples providing a fairly complete illustration of the present understanding of dynamic tunnelling processes are presented. The bibliography includes 45 references.

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