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Phosphorus-containing nucleophiles in reactions with polyfluorinated organic compounds

Georgii Georgievich Furin 1
Georgii Georgievich Furin
1 Novosibirsk Institute of Organic Chemistryof the Siberian Branch of Russian Academy of Sciences
10.1070/RC1993v062n03ABEH000016
Published 30 November 1992
Communication , Volume 62, Issue 3, 243-259
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Furin G. G. Phosphorus-containing nucleophiles in reactions with polyfluorinated organic compounds // Russian Chemical Reviews. 1993. Vol. 62. No. 3. pp. 243-259.
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Furin G. G. Phosphorus-containing nucleophiles in reactions with polyfluorinated organic compounds // Russian Chemical Reviews. 1993. Vol. 62. No. 3. pp. 243-259.
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TY - JOUR
DO - 10.1070/RC1993v062n03ABEH000016
UR - https://rcr.colab.ws/publications/10.1070/RC1993v062n03ABEH000016
TI - Phosphorus-containing nucleophiles in reactions with polyfluorinated organic compounds
T2 - Russian Chemical Reviews
AU - Furin, Georgii Georgievich
PY - 1993
DA - 1992/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 243-259
IS - 3
VL - 62
ER -
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@article{1993_Furin,
author = {Georgii Georgievich Furin},
title = {Phosphorus-containing nucleophiles in reactions with polyfluorinated organic compounds},
journal = {Russian Chemical Reviews},
year = {1993},
volume = {62},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1993v062n03ABEH000016},
number = {3},
pages = {243--259},
doi = {10.1070/RC1993v062n03ABEH000016}
}
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Furin, Georgii Georgievich. “Phosphorus-containing nucleophiles in reactions with polyfluorinated organic compounds.” Russian Chemical Reviews, vol. 62, no. 3, Nov. 1993, pp. 243-259. https://rcr.colab.ws/publications/10.1070/RC1993v062n03ABEH000016.
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Abstract

The review presents a compilation of new expelimental data on the reactions of phosphorus-containing nucleophiles [triphenylphosphine, trialkylphosphines, trialkyl phosphites, phosphorus tris(diethylamide), etc.] with perfluorinated olefins and aromatic and heterocyclic compounds, leading to substances both with and without a phosphorus atom. It is shown that the interaction of phosphorus tris(diethylamide) and trialkylphosphines with organic polyfluoro-compounds and perfluoroolefins leads to the formation of phosphoranes, the decomposition of which is accompanied by the generation of aryl and alkenyl anions. The reactions of these anions with C-electrophiles and compounds containing mobile halogen atoms are examined. In addition, the pathways in the Arbuzov reaction involving a series of unsaturated perfluorinated compounds are analysed. Possible applications of these reactions in organic synthesis are demonstrated. The bibliography includes 120 references.

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