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Relation between molecular and chemical dynamics for elementary radical reactions in viscous media

Rakhim Rashidovich Rakhimov 1
Rakhim Rashidovich Rakhimov
, 
Alexandr Ivanovich Prokof'ev 2
Alexandr Ivanovich Prokof'ev
, 
Yakov Sergeevich Lebedev 3
Yakov Sergeevich Lebedev
1 V. I. Nikitin Institute of Chemistry, Dushanbe
2 A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, Moscow
3 N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow
10.1070/RC1993v062n06ABEH000030
Published 30 November 1992
Communication , Volume 62, Issue 6, 509-526
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Rakhimov R. R., Prokof'ev A. I., Lebedev Y. S. Relation between molecular and chemical dynamics for elementary radical reactions in viscous media // Russian Chemical Reviews. 1993. Vol. 62. No. 6. pp. 509-526.
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Rakhimov R. R., Prokof'ev A. I., Lebedev Y. S. Relation between molecular and chemical dynamics for elementary radical reactions in viscous media // Russian Chemical Reviews. 1993. Vol. 62. No. 6. pp. 509-526.
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TY - JOUR
DO - 10.1070/RC1993v062n06ABEH000030
UR - https://rcr.colab.ws/publications/10.1070/RC1993v062n06ABEH000030
TI - Relation between molecular and chemical dynamics for elementary radical reactions in viscous media
T2 - Russian Chemical Reviews
AU - Rakhimov, Rakhim Rashidovich
AU - Prokof'ev, Alexandr Ivanovich
AU - Lebedev, Yakov Sergeevich
PY - 1993
DA - 1992/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 509-526
IS - 6
VL - 62
ER -
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@article{1993_Rakhimov,
author = {Rakhim Rashidovich Rakhimov and Alexandr Ivanovich Prokof'ev and Yakov Sergeevich Lebedev},
title = {Relation between molecular and chemical dynamics for elementary radical reactions in viscous media},
journal = {Russian Chemical Reviews},
year = {1993},
volume = {62},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1993v062n06ABEH000030},
number = {6},
pages = {509--526},
doi = {10.1070/RC1993v062n06ABEH000030}
}
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Rakhimov, Rakhim Rashidovich, et al. “Relation between molecular and chemical dynamics for elementary radical reactions in viscous media.” Russian Chemical Reviews, vol. 62, no. 6, Nov. 1993, pp. 509-526. https://rcr.colab.ws/publications/10.1070/RC1993v062n06ABEH000030.
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Abstract

Excperimental data on the effect of viscosity on the kinetics of elementary chernical reactions of free radicals in solid matrices and viscous solutions are analysed. The dynamic effects in EPR spectroscopy are used for the simultaneous investigation of molecular and chemical dynamics. The intramolecular transformations in free radicals and the spin exchange in biradicals are considered. It is shown that the rates of such intramolecular reactions are controlled by the molecular dynamics of the chemical cage. The bibliography includes 58 references.

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