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Glycals in enantiospecific synthesis

Alexander Genrikhovich Tolstikov 1
Alexander Genrikhovich Tolstikov
, 
Genrikh Alexandrovich Tolstikov 1
Genrikh Alexandrovich Tolstikov
1 Institute of Organic Chemistry, Ufa Scientific Centre of RAS
10.1070/RC1993v062n06ABEH000034
Published 30 November 1992
Communication , Volume 62, Issue 6, 579-601
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Tolstikov A. G., Tolstikov G. A. Glycals in enantiospecific synthesis // Russian Chemical Reviews. 1993. Vol. 62. No. 6. pp. 579-601.
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Tolstikov A. G., Tolstikov G. A. Glycals in enantiospecific synthesis // Russian Chemical Reviews. 1993. Vol. 62. No. 6. pp. 579-601.
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TY - JOUR
DO - 10.1070/RC1993v062n06ABEH000034
UR - https://rcr.colab.ws/publications/10.1070/RC1993v062n06ABEH000034
TI - Glycals in enantiospecific synthesis
T2 - Russian Chemical Reviews
AU - Tolstikov, Alexander Genrikhovich
AU - Tolstikov, Genrikh Alexandrovich
PY - 1993
DA - 1992/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 579-601
IS - 6
VL - 62
ER -
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@article{1993_Tolstikov,
author = {Alexander Genrikhovich Tolstikov and Genrikh Alexandrovich Tolstikov},
title = {Glycals in enantiospecific synthesis},
journal = {Russian Chemical Reviews},
year = {1993},
volume = {62},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1993v062n06ABEH000034},
number = {6},
pages = {579--601},
doi = {10.1070/RC1993v062n06ABEH000034}
}
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Tolstikov, Alexander Genrikhovich, and Genrikh Alexandrovich Tolstikov. “Glycals in enantiospecific synthesis.” Russian Chemical Reviews, vol. 62, no. 6, Nov. 1993, pp. 579-601. https://rcr.colab.ws/publications/10.1070/RC1993v062n06ABEH000034.
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Abstract

The reactions of 1,2-unsaturated sugars (glycals) are considered in this review in relation to problems of the enantiospecific synthesis of natural products, their fragments, and their analogues. The reactions occurring both with retention of the heterocycle and those carried out with the aim of obtaining open chain chiral units are discussed. It is shown that the use of glycals as a stock of chiral substances which determine the configuration of the asymmetric centres in the target products of multistage synthesis is promising. Schemes for the synthesis of natural products of different types are considered: O- and C-glycosides, nucleosides, oligosaccharides, pheromones, antibiotics, toxins, glycosphingolipids, etc. The bibliography includes 161 references.

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