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Influence of the polarity of the medium on the electronic structure and energetics of molecules in solutions

Inessa Pavlovna Gol'dshtein 1
Inessa Pavlovna Gol'dshtein
, 
Èduard Sergeevich Petrov 1
Èduard Sergeevich Petrov
1 Karpov Institute of Physical Chemistry, Moscow
10.1070/RC1993v062n07ABEH000036
Published 30 November 1992
Communication , Volume 62, Issue 7, 625-636
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Gol'dshtein I. P., Petrov È. S. Influence of the polarity of the medium on the electronic structure and energetics of molecules in solutions // Russian Chemical Reviews. 1993. Vol. 62. No. 7. pp. 625-636.
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Gol'dshtein I. P., Petrov È. S. Influence of the polarity of the medium on the electronic structure and energetics of molecules in solutions // Russian Chemical Reviews. 1993. Vol. 62. No. 7. pp. 625-636.
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TY - JOUR
DO - 10.1070/RC1993v062n07ABEH000036
UR - https://rcr.colab.ws/publications/10.1070/RC1993v062n07ABEH000036
TI - Influence of the polarity of the medium on the electronic structure and energetics of molecules in solutions
T2 - Russian Chemical Reviews
AU - Gol'dshtein, Inessa Pavlovna
AU - Petrov, Èduard Sergeevich
PY - 1993
DA - 1992/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 625-636
IS - 7
VL - 62
ER -
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@article{1993_Gol'dshtein,
author = {Inessa Pavlovna Gol'dshtein and Èduard Sergeevich Petrov},
title = {Influence of the polarity of the medium on the electronic structure and energetics of molecules in solutions},
journal = {Russian Chemical Reviews},
year = {1993},
volume = {62},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1993v062n07ABEH000036},
number = {7},
pages = {625--636},
doi = {10.1070/RC1993v062n07ABEH000036}
}
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Gol'dshtein, Inessa Pavlovna, and Èduard Sergeevich Petrov. “Influence of the polarity of the medium on the electronic structure and energetics of molecules in solutions.” Russian Chemical Reviews, vol. 62, no. 7, Nov. 1993, pp. 625-636. https://rcr.colab.ws/publications/10.1070/RC1993v062n07ABEH000036.
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Abstract

Recent data on the effect of the polarity of the medium on the states of solute molecules having different types of chemical bond in are reviewed. The changes in electronic structure and in the energetics of the molecules are discussed, and their influence in the physicochemical properties and role of the molecules in various liquid-phase processes (tautomeric and conformational transformations, nucleophilic substitution, proton transfer) is examined. Special attention is paid to the new concept of preferential stabilisation of molecular and of ionic forms of salts and of complexes with intermolecular hydrogen bonds in media of different polarity. The bibliography includes 98 references.

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