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Iron-subgroup metal carbonyls in reactions with olefins having functional group substituents

Leonid Vasil'evich Rybin 1
Leonid Vasil'evich Rybin
, 
Margarita Iosifovna Rybinskaya 1
Margarita Iosifovna Rybinskaya
1 A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, Moscow
10.1070/RC1993v062n07ABEH000037
Published 30 November 1992
Communication , Volume 62, Issue 7, 637-646
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Rybin L. V., Rybinskaya M. I. Iron-subgroup metal carbonyls in reactions with olefins having functional group substituents // Russian Chemical Reviews. 1993. Vol. 62. No. 7. pp. 637-646.
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Rybin L. V., Rybinskaya M. I. Iron-subgroup metal carbonyls in reactions with olefins having functional group substituents // Russian Chemical Reviews. 1993. Vol. 62. No. 7. pp. 637-646.
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TY - JOUR
DO - 10.1070/RC1993v062n07ABEH000037
UR - https://rcr.colab.ws/publications/10.1070/RC1993v062n07ABEH000037
TI - Iron-subgroup metal carbonyls in reactions with olefins having functional group substituents
T2 - Russian Chemical Reviews
AU - Rybin, Leonid Vasil'evich
AU - Rybinskaya, Margarita Iosifovna
PY - 1993
DA - 1992/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 637-646
IS - 7
VL - 62
ER -
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@article{1993_Rybin,
author = {Leonid Vasil'evich Rybin and Margarita Iosifovna Rybinskaya},
title = {Iron-subgroup metal carbonyls in reactions with olefins having functional group substituents},
journal = {Russian Chemical Reviews},
year = {1993},
volume = {62},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1993v062n07ABEH000037},
number = {7},
pages = {637--646},
doi = {10.1070/RC1993v062n07ABEH000037}
}
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Rybin, Leonid Vasil'evich, and Margarita Iosifovna Rybinskaya. “Iron-subgroup metal carbonyls in reactions with olefins having functional group substituents.” Russian Chemical Reviews, vol. 62, no. 7, Nov. 1993, pp. 637-646. https://rcr.colab.ws/publications/10.1070/RC1993v062n07ABEH000037.
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Abstract

The review covers the results of studies on the reactions of iron, ruthenium, and osmium carbonyls with olefins having functional group substituents, the behaviour of which differs significantly from that of simple olefins. Such studies have made it possible to create a new aspect of the chemistry of olefin complexes. The development of this field has led to the synthesis of previously unknown mononuclear and polynuclear complexes and to the discovery of unusual rearrangements of the complex compounds. The reactions of iron carbonyls differ from those of ruthenium and osmium carbonyls. In the last case, the hapticity of the unsaturated ligands increases and the ligands are found to be capable of giving rise to extremely unexpected structures. The present review surveys mainly the results of studies by the authors, who made a significant contribution to the development of this field. The bibliography includes 73 references.

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