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Catalytic decomposition of diazomethane as a general method for the methylenation of chemical compounds

, 
Vladimir Anatol'evich Dokitchev 2
Vladimir Anatol'evich Dokitchev
,  , 
Oleg Matveevich Nefedov 1
Oleg Matveevich Nefedov
1 N. D. Zelinskii Institute of Organic Chemistry, Moscow
2 Institute of Organic Chemistry, Ufa Scientific Centre of RAS
3 Institute of Oil Chemistry and Catalyse, Academy of Sciences of Bashkortostan, Ufa
10.1070/RC1993v062n09ABEH000048
Published 30 November 1992
Communication , Volume 62, Issue 9, 799-838
66
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Tomilov Y. V. et al. Catalytic decomposition of diazomethane as a general method for the methylenation of chemical compounds // Russian Chemical Reviews. 1993. Vol. 62. No. 9. pp. 799-838.
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Tomilov Y. V., Dokitchev V. A., Dzhemilev U. M., Nefedov O. M. Catalytic decomposition of diazomethane as a general method for the methylenation of chemical compounds // Russian Chemical Reviews. 1993. Vol. 62. No. 9. pp. 799-838.
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TY - JOUR
DO - 10.1070/RC1993v062n09ABEH000048
UR - https://rcr.colab.ws/publications/10.1070/RC1993v062n09ABEH000048
TI - Catalytic decomposition of diazomethane as a general method for the methylenation of chemical compounds
T2 - Russian Chemical Reviews
AU - Tomilov, Yury Vasil'evich
AU - Dokitchev, Vladimir Anatol'evich
AU - Dzhemilev, Usein Memetovich
AU - Nefedov, Oleg Matveevich
PY - 1993
DA - 1992/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 799-838
IS - 9
VL - 62
ER -
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@article{1993_Tomilov,
author = {Yury Vasil'evich Tomilov and Vladimir Anatol'evich Dokitchev and Usein Memetovich Dzhemilev and Oleg Matveevich Nefedov},
title = {Catalytic decomposition of diazomethane as a general method for the methylenation of chemical compounds},
journal = {Russian Chemical Reviews},
year = {1993},
volume = {62},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1993v062n09ABEH000048},
number = {9},
pages = {799--838},
doi = {10.1070/RC1993v062n09ABEH000048}
}
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Tomilov, Yury Vasil'evich, et al. “Catalytic decomposition of diazomethane as a general method for the methylenation of chemical compounds.” Russian Chemical Reviews, vol. 62, no. 9, Nov. 1993, pp. 799-838. https://rcr.colab.ws/publications/10.1070/RC1993v062n09ABEH000048.
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Abstract

The principal advances and trends in the application of diazomethane as a methylenating agent in synthetic chemistry using transition and non-transition metal compounds as catalysts are surveyed and analysed. The catalytic reactions of diazomethane with olefins, acethylenes, aromatic compounds, ketones, alcohols and amines are examined. A systematic account is given of data concerning the influence of the structure of the initial substrates and of the nature of the catalyst components on the regio- and stereo-selectivity of the reactions considered. The possibilities of the catalytic conversion by diazomethane (generated in situ) of unsaturated compounds into cyclopropane derivatives are considered. The bibliography includes 284 references.

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