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Orbital interactions through space and through σ-bonds

Èsfir' Isaakovna Brodskaya 1
Èsfir' Isaakovna Brodskaya
, 
Gennadii Vul'fovich Ratovskii 2
Gennadii Vul'fovich Ratovskii
, 
Mikhail Grigor'evich Voronkov 1
Mikhail Grigor'evich Voronkov
1 Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
2 Institute of Petroleum and Carbon Synthesis of the Irkutsk State University
10.1070/RC1993v062n10ABEH000054
Published 30 November 1992
Communication , Volume 62, Issue 10, 919-933
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Brodskaya È. I., Ratovskii G. V., Voronkov M. G. Orbital interactions through space and through σ-bonds // Russian Chemical Reviews. 1993. Vol. 62. No. 10. pp. 919-933.
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Brodskaya È. I., Ratovskii G. V., Voronkov M. G. Orbital interactions through space and through σ-bonds // Russian Chemical Reviews. 1993. Vol. 62. No. 10. pp. 919-933.
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TY - JOUR
DO - 10.1070/RC1993v062n10ABEH000054
UR - https://rcr.colab.ws/publications/10.1070/RC1993v062n10ABEH000054
TI - Orbital interactions through space and through σ-bonds
T2 - Russian Chemical Reviews
AU - Brodskaya, Èsfir' Isaakovna
AU - Ratovskii, Gennadii Vul'fovich
AU - Voronkov, Mikhail Grigor'evich
PY - 1993
DA - 1992/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 919-933
IS - 10
VL - 62
ER -
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@article{1993_Brodskaya,
author = {Èsfir' Isaakovna Brodskaya and Gennadii Vul'fovich Ratovskii and Mikhail Grigor'evich Voronkov},
title = {Orbital interactions through space and through σ-bonds},
journal = {Russian Chemical Reviews},
year = {1993},
volume = {62},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1993v062n10ABEH000054},
number = {10},
pages = {919--933},
doi = {10.1070/RC1993v062n10ABEH000054}
}
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Brodskaya, Èsfir' Isaakovna, et al. “Orbital interactions through space and through σ-bonds.” Russian Chemical Reviews, vol. 62, no. 10, Nov. 1993, pp. 919-933. https://rcr.colab.ws/publications/10.1070/RC1993v062n10ABEH000054.
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Abstract

The present state of one of the comparatively new theoretical concepts in organic chemistry – the interaction of two heteroatoms having a lone electron pair or of groups incorporating a π-bond through the system of σ-bonds separating them – is considered. Two mechanisms of such interactions are discussed – through space and through the σ-bonds. These interactions are assessed in terms of UV, photoelectron, and electronic transmission spectroscopic and quantum-chemical data. The influence of the above interactions on the reactivity of the molecules is illustrated. The bibliography includes 139 references.

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