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The chemistry of volatile β-diketonates and their application in the synthesis of high-temperature superconducting thin films

Gennadii Vasil'evich Bazuev 1
Gennadii Vasil'evich Bazuev
, 
Lyudmila Dmitrievna Kurbatova 1
Lyudmila Dmitrievna Kurbatova
1 Institute of Solid State Chemistry, Urals Branch of the Russian Academy of Sciences, Ekaterinburg
10.1070/RC1993v062n10ABEH000058
Published 30 November 1992
Communication , Volume 62, Issue 10, 981-989
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Bazuev G. V., Kurbatova L. D. The chemistry of volatile β-diketonates and their application in the synthesis of high-temperature superconducting thin films // Russian Chemical Reviews. 1993. Vol. 62. No. 10. pp. 981-989.
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Bazuev G. V., Kurbatova L. D. The chemistry of volatile β-diketonates and their application in the synthesis of high-temperature superconducting thin films // Russian Chemical Reviews. 1993. Vol. 62. No. 10. pp. 981-989.
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TY - JOUR
DO - 10.1070/RC1993v062n10ABEH000058
UR - https://rcr.colab.ws/publications/10.1070/RC1993v062n10ABEH000058
TI - The chemistry of volatile β-diketonates and their application in the synthesis of high-temperature superconducting thin films
T2 - Russian Chemical Reviews
AU - Bazuev, Gennadii Vasil'evich
AU - Kurbatova, Lyudmila Dmitrievna
PY - 1993
DA - 1992/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 981-989
IS - 10
VL - 62
ER -
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@article{1993_Bazuev,
author = {Gennadii Vasil'evich Bazuev and Lyudmila Dmitrievna Kurbatova},
title = {The chemistry of volatile β-diketonates and their application in the synthesis of high-temperature superconducting thin films},
journal = {Russian Chemical Reviews},
year = {1993},
volume = {62},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1993v062n10ABEH000058},
number = {10},
pages = {981--989},
doi = {10.1070/RC1993v062n10ABEH000058}
}
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Bazuev, Gennadii Vasil'evich, and Lyudmila Dmitrievna Kurbatova. “The chemistry of volatile β-diketonates and their application in the synthesis of high-temperature superconducting thin films.” Russian Chemical Reviews, vol. 62, no. 10, Nov. 1993, pp. 981-989. https://rcr.colab.ws/publications/10.1070/RC1993v062n10ABEH000058.
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Abstract

We shall examine the fundamental aspects of the chemistry of volatile β-diketonates: the dependence of their volatility on the coordination unsaturation of the complexes, on the structure of the ligands, and on the nature of the metales. The gas-phase thermal stability of the β-diketonates and the structural changes which take place when these compounds are transferred to the gas phase are discussed. The most important results on the synthesis of Y–Ba–Cu–O, Bi–Sr–Ca–Cu–O, and Tl–Ba–Ca–Cu–O by chemical vapour deposition from the gas phase are reported. The bibliography includes 106 references.

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